Influence of water and oxygen in the media on the  process of benzene- thermal synthesis of GaP nanocrystals

Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (6): 643-646. Previous Articles Next Articles

Original Articles

苯热GaP纳米微晶介质中水氧对反应过程的影响

高善民;孙树声;崔得良;黄柏标;蒋民华

山东省海洋化工科学研究院;山东大学晶体材料国家重点实验室

发布日期:2000-06-15

Influence of water and oxygen in the media on the process of benzene- thermal synthesis of GaP nanocrystals

Gao Shanmin;Sun Shusheng;Cui Deliang;Huang Baibiao;Jiang Minhua

Published:2000-06-15

Abstract

Nanometer GaP crystal was synthesized by using the benzene-thermal synthesis method with GaCl~3-ethyl ether, GaCl~3-benzene and P as the starting materials. The influence of remaining H~2O and oxygen on the results was investigated. The stability of products was studied by comparing the strength of respective chemical bonds. The results indicate that both H~2O and oxygen have obvious effects on the reaction process and may even change the direction of reaction in some case.

Key words: GALLIUM PHOSPHIDE, CRYSTALS, NANOPHASE MATERIALS, PHOSPHORUS, GALLIUM CHLORIDE

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Cite this article

Gao Shanmin;Sun Shusheng;Cui Deliang;Huang Baibiao;Jiang Minhua. Influence of water and oxygen in the media on the process of benzene- thermal synthesis of GaP nanocrystals[J]. Acta Chimica Sinica, 2000, 58(6): 643-646.

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苯热GaP纳米微晶介质中水氧对反应过程的影响

Influence of water and oxygen in the media on the process of benzene- thermal synthesis of GaP nanocrystals

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