Synthesis and structure of binuclear molybdenum oxalate

Abstract

A new compound (N~2H~6)~0~.~5[(CH~3)~4N]{[MoO(H~2O)C~2O~4]~2(μ^2-O) ~2}·H~2O was prepared and its structure was determined by X-ray diffraction analysis. The compound has two edge-shared molybdenum- oxygen octahedra and all the Mo atoms are of charge +5. Mo centers are chelated by oxalates. The crystal is monoclinic, space group P2~1/c, a=0.6059(1) nm, b=1.6658(3) nm, c=1.8249(4) nm, β=94.02(3)°, V=1. 8374(6) nm^3, R~1=0.0337, wR~2=0.0908.

Key words: MOLYBDENUM COMPLEX, OXALIC ACID P, DINUCLEAR COMPLEX, CRYSTAL STRUCTURE

CLC Number:

O611.662

Cite this article

Liu An;Zhang Shiwei. Synthesis and structure of binuclear molybdenum oxalate[J]. Acta Chimica Sinica, 2000, 58(7): 912-916.

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