Synthesis and Crystal Structure of Layer Type Inclusion Compound of Thiourea with Tetraethylammonium Tartrate and Water

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (6): 1017-1022. Previous Articles Next Articles

Original Articles

硫尿、L-酒石酸根和水为主体晶格的四乙基铵层状包合物的合成及晶体结构

石梅;张锦楠;李奇

北京师范大学化学系.北京(100875);首都医科大学化学药理学系.北京 (100054)

发布日期:2002-06-15

Synthesis and Crystal Structure of Layer Type Inclusion Compound of Thiourea with Tetraethylammonium Tartrate and Water

Shi Mei;Zhang Jinnan;Li Qi

Department of Chemistry, Beijing Normal University.Beijing(100875);Department of Chemistry and Pharmacology, Capital University of Medical Science.Beijing(100054)

Published:2002-06-15

Abstract

A new inclusion complex tetraethylammonium tartrate thiourea-water [(C_2H_5)_4N~+]_2C_4H_4O_6~(2-)·2(NH_2)_2CS·2H_2O has been prepared and characterized by X-ray crystallography. Crystal data: Mo Kα radiation, P2_1 space group with lattice parameters a = 0.7727(2) nm, b = 1.4707(4) nm, c = 1.4645(4) nm, β = 95.161(5)°, Z = 2, R_1 = 0. 0488 for 5421 observed data. In the crystal structure of the title compound, the water molecules are located between the parallel double ribbons formed by [(NH_2)_2CS·(C_4H_4O_4~(2-))·(NH_2)_2CS] trimers and link them by hydrogen bonds to generate layer type host lattice. The tetraethylammonium cations are sandwiched between the puckered layers.

Key words: CLATHRATES, CRYSTAL STRUCTURE, HYDROGEN BONDS, THIOUREAS, TARTARIC ACID, XRD

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Shi Mei;Zhang Jinnan;Li Qi. Synthesis and Crystal Structure of Layer Type Inclusion Compound of Thiourea with Tetraethylammonium Tartrate and Water[J]. Acta Chimica Sinica, 2002, 60(6): 1017-1022.

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硫尿、L-酒石酸根和水为主体晶格的四乙基铵层状包合物的合成及晶体结构

Synthesis and Crystal Structure of Layer Type Inclusion Compound of Thiourea with Tetraethylammonium Tartrate and Water

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