A CIDEP Study of Photolyzed Benzaldehyde Radicals in TX-100 and SDBS Micelles

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (7): 1230-1234. Previous Articles Next Articles

Original Articles

表面活性剂TX-100与SDBS胶束中光解苯甲醛自由基的化学诱导动态电子极化

陆同兴;涂兴华;牟建海;李干佐

安徽师范大学物理系,芜湖(241000);山东大学,济南(250100)

发布日期:2002-07-15

A CIDEP Study of Photolyzed Benzaldehyde Radicals in TX-100 and SDBS Micelles

Lu Tongxing;Tu Xinghua;Mu Jianhai;Li Ganzuo

Department of Physics, Anhui Normal University,Wuhan(241000);Key Lab for Colloid & Interface Chemistry of State Education Ministry, Shandong University,Jinan(250100)

Published:2002-07-15

Abstract

The time-resolved electron spin resonance (TRESR) spectra and chemically induced dynamic electron polarization (CIDEP) phenomena, obtained from laser flash photolysis of benzaldehyde (BA) in ethylene glycol, SDBS and TX-100 micellar solutions, were investigated. It was shown that α-hydroxybenzyl and benzoyl radicals were generated via hydrogen abstraction of the triplet state of BA from the systems and itself. The polarization spectrum lines confirmed the radical pair mechanism (RPM) in SDBS micelles as well as the triplet mechanism (TM) in TX-100 micelles. The computer simulation of the CIDEP spectra further confirmed the generation and polarization mechanisms of the radicals.

Key words: MICELLE, BENZALDEHYDE, ESR, ETHANEDIOL, PHOTOLYSIS, POLARIZATION, FREE RADICAL

CLC Number:

O644

Cite this article

Lu Tongxing;Tu Xinghua;Mu Jianhai;Li Ganzuo. A CIDEP Study of Photolyzed Benzaldehyde Radicals in TX-100 and SDBS Micelles[J]. Acta Chimica Sinica, 2002, 60(7): 1230-1234.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Shan Li, Junxin Lu, Jie Liu, Lvqi Jiang, Wenbin Yi. Electrochemical Synthesis of α-Fluoroalkylated Ketones using Sodium Fluoroalkylsulfinate [J]. Acta Chimica Sinica, 2024, 82(2): 110-114.
[2]	Chenyu Liao, Shanwei Guo, Meiwei Huang, Yong Guo, Qing-Yun Chen, Chao Liu, Yunwen Zhang. Synthesis and Properties of Fluoroether Phosphocholine [J]. Acta Chimica Sinica, 2024, 82(1): 46-52.
[3]	Jianqiang Chen, Gangguo Zhu, Jie Wu. Recent Advances in Radical-Based Dehydroxylation of Hydroxyl Groups via Oxalates [J]. Acta Chimica Sinica, 2023, 81(11): 1609-1623.
[4]	Hongdan Zhang, Xinyu Lan, Peng Cheng. Advances in Hydroxyl Free Radical Assisted Synthesis of Zeolite [J]. Acta Chimica Sinica, 2023, 81(1): 100-110.
[5]	Xiaoke Hu, Xiaoying Shang, Ping Huang, Wei Zheng, Xueyuan Chen. Polarized Upconversion Luminescence from a Single NaYF₄:Yb³⁺/Er³⁺ Microrod for Orientation Tracking^※ [J]. Acta Chimica Sinica, 2022, 80(3): 244-248.
[6]	Zhao, Yong, Li, Shihong, Zhang, Miaomiao, Liu, Feng. Synthesis of β,γ-Unsaturated Esters and γ-Ketone Esters with Amino Acid Ester-Derived Katritzky Salts [J]. Acta Chimica Sinica, 2019, 77(9): 916-921.
[7]	Ye, Shengqing, Wu, Jie. 4-Substituted Hantzsch Esters as Alkylation Reagents in Organic Synthesis [J]. Acta Chimica Sinica, 2019, 77(9): 814-831.
[8]	Xiao, Yingxia, Liu, Zhong-Quan. Radical-Promoted Cross Dehydrogenative Coupling of Ketones and Esters with Electron-Rich Heteroarenes [J]. Acta Chimica Sinica, 2019, 77(9): 874-878.
[9]	Zhao Weiwei, Wang Yilin. Development of Surfactant Application in Wastewater Treatment [J]. Acta Chim. Sinica, 2019, 77(8): 717-728.
[10]	Jiao Yang, Zhang Xi. Supramolecular Free Radicals: Fabrication, Modulation and Functions [J]. Acta Chim. Sinica, 2018, 76(9): 659-665.
[11]	Gu Zhengyang, Ji Shunjun. Recent Advances in Cobalt Catalyzed Isocyanide Coupling Reactions [J]. Acta Chim. Sinica, 2018, 76(5): 347-356.
[12]	Zhang Bei, Chang Baisong, Sun Taolei. Synthesis and Study of Hypoxia-Responsive Micelles Based on Hyaluronic Acid [J]. Acta Chim. Sinica, 2018, 76(1): 35-42.
[13]	Wang Dehong, Zhang Long, Luo Sanzhong. Photo-induced Catalytic Asymmetric Free Radical Reactions [J]. Acta Chim. Sinica, 2017, 75(1): 22-33.
[14]	Wan Gang, Fu Yu'ang, Guo Jianing, Xiang Zhonghua. Photoelectronic Porous Covalent Organic Materials: Research Progress and Perspective [J]. Acta Chim. Sinica, 2015, 73(6): 557-578.
[15]	Sha Min, Zhang Ding, Pan Renming, Xing Ping, Jiang Biao. Synthesis and Properties Study of Novel Branched Fluorinated Surfactants with CF₃CF₂CF₂C(CF₃)₂ Group [J]. Acta Chim. Sinica, 2015, 73(5): 395-402.

表面活性剂TX-100与SDBS胶束中光解苯甲醛自由基的化学诱导动态电子极化

A CIDEP Study of Photolyzed Benzaldehyde Radicals in TX-100 and SDBS Micelles

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments