Structure of Octupolar Molecule TSTA and Its Optical Properties

Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (3): 307-311. Next Articles

Original Articles

2,4,6-三苯乙烯基均三嗪（TSTA）的结构及其光学性质

崔月芝;方奇;薛刚;于文涛;雷虹;刘志强

山东大学;信息科学与工程学院

发布日期:2003-03-15

Structure of Octupolar Molecule TSTA and Its Optical Properties

Cui Yuezhi;Fang Qi;Xue Gang;Yu Wentao;Lei Hong;Liu Zhiqiang

State Key Laboratory of Crystal Material,Shandong;School of Information Science and Engineering,Light Industry College of Shandong

Published:2003-03-15

Abstract

2,4,6-Tristyryl-s-triazine (TSTA, C_(27)H_(21)N_3) is an octupolar compound with a molecular configuration of a slightly curved planar triangle. Its crystal is determined to belong to the orthorhombic space group Cmc2_1 (No. 36) by a four-circle diffractometer. The polar non-centrosymmetric crystal structure accounts for its significant second-harmonic generation (SHG) efficiency, which is 1.8 times as large as that of urea under 1064 nm input laser pulses. The good thermal stability (melting point 225 -227℃) and excellent transparency (with peak position at 322 nm in absorption spectrum) qualify it as a promising SHG material.

Key words: STYRENE P, TRIAZINE P, CRYSTAL STRUCTURE, XRD, NON LINEAR OPTICS, THERMAL STABILITY

CLC Number:

O644

Cite this article

Cui Yuezhi;Fang Qi;Xue Gang;Yu Wentao;Lei Hong;Liu Zhiqiang. Structure of Octupolar Molecule TSTA and Its Optical Properties[J]. Acta Chimica Sinica, 2003, 61(3): 307-311.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Han Zha, Jin Fang, Lingpeng Yan, Yongzhen Yang, Changqi Ma. Research Progress of Thermal Failure Mechanism and Ternary Blending to Improve Thermal Stability of Organic Solar Cells [J]. Acta Chimica Sinica, 2023, 81(2): 131-145.
[3]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[4]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[5]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[6]	Junhui Miao, Zicheng Ding, Jun Liu, Lixiang Wang. Research Progress in Organic Solar Cells Based on Small Molecule Donors and Polymer Acceptors [J]. Acta Chimica Sinica, 2021, 79(5): 545-556.
[7]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[8]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[9]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[10]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[11]	Yan Zhuojun, Yuan Ye, Liu Jia, Li Qin, Nguyen Nam-Trung, Zhang Daming, Tian Yuyang, Zhu Guangshan. Targeted Syntheses of Charged Porous Aromatic Frameworks for Iodine Enrichment and Release [J]. Acta Chim. Sinica, 2016, 74(1): 67-73.
[12]	Dong Lu, Zheng Chunying, Zhou Pei, Shi Rufei, Li Hui. Advances in Crystallography of Coordination Complexes on Main Group Metals with Amino Acid Ligands [J]. Acta Chimica Sinica, 2014, 72(9): 981-1000.
[13]	Wan Yang, Zheng Qiaoji, Lin Dunmin. Recent Development of LiMnPO₄ as Cathode Materials of Lithium-ion Batteries [J]. Acta Chimica Sinica, 2014, 72(5): 537-551.
[14]	Zhang Tingting, Wang Haitao, Ma Heping, Sun Fuxing, Cui Xiaoqiang, Zhu Guangshan. Construction and Characterization of Pyrene-alkyne Based Porous Frameworks [J]. Acta Chimica Sinica, 2013, 71(12): 1598-1602.
[15]	Han Cong, Xu Zhe, Diao Chunhua, Chen Xin, Liu Jing, Guo Minjie, Fan Zhi. Self-assembly Behavior of Interlocked Helical Supramolecule of Cyclodextrin Modified by 2-Furanmethanethiol [J]. Acta Chimica Sinica, 2013, 71(03): 439-442.

2,4,6-三苯乙烯基均三嗪（TSTA）的结构及其光学性质

Structure of Octupolar Molecule TSTA and Its Optical Properties

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments