Radical Addition Reaction between Perfluoro- and ω-H- Perfluorodiacyl Peroxides and C_(60)

Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (5): 736-741. Previous Articles Next Articles

Original Articles

全氟和ω-H-全氟酰基过氧化物与C60的自由基加成反应——全氟和ω-H-全氟烷基化C60的合成

贺海鹰;赵成学

上海交通大学化学系

发布日期:2003-05-15

Radical Addition Reaction between Perfluoro- and ω-H- Perfluorodiacyl Peroxides and C_(60)

He Haiying;Zhao Chengxue

Department of Chemistry, Shanghai Jiaotong University

Published:2003-05-15

Abstract

The radical addition reactions between peifluoro- and a>-.//- perfluorodiacyl peroxides and Cgo were studied by EPR determination of the radical intermediates, GC analysis and NMR characterization of the products. The per(poly)fluoroalkylated Qo shows excellent hydro and lipophobicity.

Key words: C60, FLUORINE COMPOUNDS, PEROXIDE, ALKYLATION, FREE RADICAL REACTION, ADDITION REACTION, CHEMICLAL MODIFICATION, ACYL GROUP, PR

CLC Number:

O631.3

Cite this article

He Haiying;Zhao Chengxue. Radical Addition Reaction between Perfluoro- and ω-H- Perfluorodiacyl Peroxides and C_(60)[J]. Acta Chimica Sinica, 2003, 61(5): 736-741.

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全氟和ω-H-全氟酰基过氧化物与C60的自由基加成反应——全氟和ω-H-全氟烷基化C60的合成

Radical Addition Reaction between Perfluoro- and ω-H- Perfluorodiacyl Peroxides and C_(60)

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