Synthesis, Crystal Structure and Electrochemical Properties of a Ferrocenecarboxylato-Bridged Lanthanum(Ⅲ) Dimer

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (11): 1060-1064. Previous Articles Next Articles

二茂铁单甲酸根桥联的镧二聚体的合成、晶体结构及电化学性质

李纲, 侯红卫, 李林科, 王宇飞, 孟祥茹, 朱玉, 樊耀亭

郑州大学化学系, 郑州, 450052

投稿日期:2003-10-31 修回日期:2004-02-02 发布日期:2014-02-17
通讯作者: 侯红卫,E-mail:houhongv@zzu.edu.cn E-mail:houhongv@zzu.edu.cn
基金资助:
河南省高等学校创新人才工程和河南省杰出青年基金资助项目

Synthesis, Crystal Structure and Electrochemical Properties of a Ferrocenecarboxylato-Bridged Lanthanum(Ⅲ) Dimer

LI Gang, HOU Hong-Wei, LI Lin-Ke, WANG Yu-Fei, MENG Xiang-Ru, ZHU Yu, FAN Yao-Ting

Department of Chemistry, Zhengzhou University, Zhengzhou 450052

Received:2003-10-31 Revised:2004-02-02 Published:2014-02-17

Abstract

A novel dimer [La₂(μ₂ η²OOCFc)₂(OOCFc)₄(H₂O)₄]·2HOOCFc was obtained by the reaction of La(NO₃)₂ ·6H₂O with sodium ferrocenecarboxylate in methanol solution. X-ray structural analysis reveals that in the compound two La(Ⅲ) ions are bridged by two ferrocenecarboxylate anions as asymmetrically bridging ligands, leading to dimeric cores, [La₂(μ₂OOCFc)₂]. Each Ln(Ⅲ) ion has an irregular polyhedral coordination environment with nine coordinated oxygen atoms derived from the ferrocenecarboxylate ligands and coordinated water molecules. In its solid-state structure, [La₂(μ₂η²OOCFc)₂(OOCFc) 4(H₂O)₄] groups are joined together by O...H-O hydrogen bonds forming a one-dimensional infinite chain. The solution state differential pulse voltammetries of title compound and the corresponding ligand are investigated in the DMF solution.

Key words: dimer, lanthanum(Ⅲ), sodium ferrocenecarboxylate, crystal structure, electrochemical property

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LI Gang, HOU Hong-Wei, LI Lin-Ke, WANG Yu-Fei, MENG Xiang-Ru, ZHU Yu, FAN Yao-Ting. Synthesis, Crystal Structure and Electrochemical Properties of a Ferrocenecarboxylato-Bridged Lanthanum(Ⅲ) Dimer[J]. Acta Chimica Sinica, 2004, 62(11): 1060-1064.

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二茂铁单甲酸根桥联的镧二聚体的合成、晶体结构及电化学性质

Synthesis, Crystal Structure and Electrochemical Properties of a Ferrocenecarboxylato-Bridged Lanthanum(Ⅲ) Dimer

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