Comparison Study of Large and Nano-size NiO for Oxidative Dehydrogenation of Ethane to Ethylene

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (18): 1678-1682. Previous Articles Next Articles

乙烷在纳米氧化镍上温和氧化脱氢制乙烯

吴瑛, 陈铜, 操小栋, 翁维正, 张晋芬, 万惠霖

厦门大学化学系固体表面物理国家重点实验室, 厦门, 361005

投稿日期:2004-04-14 修回日期:2004-08-13 发布日期:2014-02-17
通讯作者: 陈铜、万惠霖,E-mail:hlwan@xmu.edu.cn E-mail:hlwan@xmu.edu.cn
基金资助:
国家重点基础研究发展规划项目(No.G1999022408)及福建自然科学基金(No.E0210002)资助项目.

Comparison Study of Large and Nano-size NiO for Oxidative Dehydrogenation of Ethane to Ethylene

WU Ying, CHEN Tong, CAO Xiao-Dong, WENG Wei-Zheng, ZHANG Jin-Fen, WAN Hui-Lin

State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry and Institute of Physical Chemistry, Xiamen University, Xiamen 361005

Received:2004-04-14 Revised:2004-08-13 Published:2014-02-17

Abstract

Nano size nickel oxide prepared by sol-gel method has better ethane oxidative dehydrogenation activity at lower temperature than by other methods. The diameter of particles calcinated at 380℃ is about 8 nm. Compared with large size nickel oxide catalyst, the reaction temperature over nano NiO was lowered about 125℃ when the same ethylene yield was obtained. The nickel oxide catalysts calcinated at different temperatures were characterized by BET, TPR, TPD, XPS, etc. And the particles size and its relationship with activation of oxygen and reaction activity were investigated.

Key words: oxidative dehydrogenation of ethane, nano, nickel oxide, sol-gel

Cite this article

WU Ying, CHEN Tong, CAO Xiao-Dong, WENG Wei-Zheng, ZHANG Jin-Fen, WAN Hui-Lin. Comparison Study of Large and Nano-size NiO for Oxidative Dehydrogenation of Ethane to Ethylene[J]. Acta Chimica Sinica, 2004, 62(18): 1678-1682.

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乙烷在纳米氧化镍上温和氧化脱氢制乙烯

Comparison Study of Large and Nano-size NiO for Oxidative Dehydrogenation of Ethane to Ethylene

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