Preparation of Nano-particle Copper by Chemical Reduction

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (23): 2365-2368. Previous Articles

化学还原法制备纳米铜

林荣会^1,3, 方亮¹, 郗英欣², 邵艳霞²

1. 西安交通大学材料科学与工程学院, 西安, 710049;
2. 西安交通大学应用化学系, 西安, 710049;
3. 青岛理工大学机电工程学院, 青岛, 266033

投稿日期:2003-11-25 修回日期:2004-07-09 发布日期:2014-02-17
通讯作者: 方亮,E-mail:fangl@mail.xjtu.edu.cn E-mail:fangl@mail.xjtu.edu.cn

Preparation of Nano-particle Copper by Chemical Reduction

LIN Rong-Hui^1,3, FANG Liang¹, XI Ying-Xin², SHAO Yan-Xia²

1. School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049;
2. Department of Applied Chemistry, Xi'an Jiaotong University, Xi'an 710049;
3. Shool of Mechanical and Electrical Engineering, Qingdao University of Technology, Qi

Received:2003-11-25 Revised:2004-07-09 Published:2014-02-17

Abstract

Nano-particle copper used for modifying phenol formaldehyde resin has been successfully prepared by reduction with KBH₄ as reductant and CuSO₄ as oxidant, and by filling with PVP and other auxiliary reagents.XRD and TEM were conducted to characterize the structure of the prepared copper particles.The results showed that the size of nano-particle copper is distributed in the range of 10～50 nm in diameter and the nano powders are with spherical geometry.The reaction course of BH₄^- and Cu²⁺ was approached.It was deduced that the reaction course underwent in three steps: the first is the reduction of Cu, the second is the two competitive reactions of produced H⁺ with BH₄^- and OH^-, respectively, and the third is the hydrolysis of boron.In this reaction, the molar ratio of KBH₄ to CuSO₄ consumed is 2:1.

Key words: reduction, nano-particle copper, protective agent, reaction course

Cite this article

LIN Rong-Hui, FANG Liang, XI Ying-Xin, SHAO Yan-Xia. Preparation of Nano-particle Copper by Chemical Reduction[J]. Acta Chimica Sinica, 2004, 62(23): 2365-2368.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Yi, Y.-H. Prog. Chem. Ind. Eng. 2001, (9), 13 (in Chinese).(伊延会, 化工进展, 2001, (9), 13.)
[2] Zhang, Y.-H. Chin. J. Rare Metals 1997, 21(6), 451 (in Chinese).(张燕红, 稀有金属, 1997, 21(6), 451.)
[3] Heino, P.; Ristolainen, E. Nanostruct. Mater. 1999, (5), 587.
[4] Sanders, P. G.; Truncone, S. A.; Scott, W. Acta Mater. 1997, (10), 4019.
[5] Wu, Z.-G. J. Funct. Polym. 2001, 14(4), 449 (in Chinese).(吴增刚, 功能高分子学报, 2001, 14(4), 449.)
[6] Zhao, A.-C. Polym. Bull. 2001, (1), 74 (in Chinese).(赵安赤, 高分子通报, 2001, (1), 74.)
[7] Wang, L.-J.; Guo, C.-W. Acta Chim. Sinica 2002, 60, 1125 (in Chinese).(王利军, 郭昌文, 化学学报, 2002, 60, 1125.)
[8] Yan, G.-H. Mater. Rev. 1997, (11), 16 (in Chinese).(严红革, 材料导报, 1997, (11), 16.)
[9] Chen, Z.-Y. Acta Metallurgica Sinica 1992, 28, 169 (in Chinese).(陈祖耀, 金属学报, 1992, 28, 169.)
[10] Huang, J.-S.; Ren, S.; Liu, Y.-X. J. Guangdong Univ. Technol. 2003, 20, 6 (in Chinese).(黄钧声, 任山, 刘延兴, 广东工业大学学报, 2003, 20, 6.)
[11] Chen, Q.-C.; Yang, H.-F. Phys. Test. Chem. Anal. P. B.: Chem. Anal. 1997, 33, 179 (in Chinese).(陈青川, 杨惠芬, 理化检测化学分册, 1997, 33, 179.)
[12] Li, Z.-W.; Zhu, Y.-F. Acta Chim. Sinica 2003, 61, 1484 (in Chinese).(李宗威, 朱永法, 化学学报, 2003, 61, 1484.)
[13] Liao, R.; Zhou, D.-L.; Zhang, W.-Z. Sichuan Nonferrous Metals 2003, (2), 28 (in Chinese).(廖戎, 周大利, 张王志, 四川有色金属, 2003, (2), 28.)
[14] Jiang, X.-X.; Shen, W. In The Fundamentals and Practice of Electroless Plating, Ed.: Zhou, R. F., National Defence lndustry Press, Bejing, 2000, p. 21 (in Chinese).(姜晓霞, 沈伟, 化学镀理论及实践, 周润芬主编, 国防工业出版社, 北京, 2000, p. 21.)

[1]	Ping Li, Qiyu Yang, Jing Zeng, Ran Zhang, Qiuyan Chen, Fei Yan. Effect of Fluorine Doping on the Performance of Reversible Solid Oxide Cells and Related Kinetic Studies [J]. Acta Chimica Sinica, 2024, 82(1): 36-45.
[2]	Yuhan Wu, Dongdong Zhang, Hongyu Yin, Zhengnan Chen, Wen Zhao, Yuhua Chi. Density Functional Theory Study of Janus In₂S₂X Photocatalytic Reduction of CO₂ under “Double Carbon” Target [J]. Acta Chimica Sinica, 2023, 81(9): 1148-1156.
[3]	Wei Hou, Yancai Yao, Lizhi Zhang. Advances in Electrochemical Reductive Removal of Oxyanions in Water^★ [J]. Acta Chimica Sinica, 2023, 81(8): 979-989.
[4]	Jianchuan Liu, Cuiyan Li, Yaozu Liu, Yujie Wang, Qianrong Fang. Highly-Stable Two-Dimensional Bicarbazole-based sp²-Carbon-conjugated Covalent Organic Framework for Efficient Electrocatalytic Oxygen Reduction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 884-890.
[5]	Jia Liu, Guanghai Chen, Yiqun Chen, Jietao Jiang, Xiao Xiao, Qiang Wu, Lijun Yang, Xizhang Wang, Zheng Hu. Boosting the Supercapacitance Performance of Mesostructured Carbon Nanocages by Enlarging Pore Sizes via Carbothermal Reduction^★ [J]. Acta Chimica Sinica, 2023, 81(7): 709-716.
[6]	Huang Jiapian, Liu Fei, Wu Jie. Recent Advances in the Transformation of Difluorocyclopropenes^★ [J]. Acta Chimica Sinica, 2023, 81(5): 520-532.
[7]	Jinjing Liu, Na Yang, Li Li, Zidong Wei. Theoretical Study on the Regulation of Oxygen Reduction Mechanism by Modulating the Spatial Structure of Active Sites on Platinum^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1478-1485.
[8]	Shaobing Yan, Long Jiao, Chuanxin He, Hailong Jiang. Pyrolysis of ZIF-67/Graphene Composite to Co Nanoparticles Confined in N-Doped Carbon for Efficient Electrocatalytic Oxygen Reduction [J]. Acta Chimica Sinica, 2022, 80(8): 1084-1090.
[9]	Dan Wang, Bo Feng, Xiaoxin Zhang, Yanan Liu, Yan Pei, Minghua Qiao, Baoning Zong. Nitrogen-doped Carbon Pyrolyzed from ZIF-8 for Electrocatalytic Oxygen Reduction to Hydrogen Peroxide [J]. Acta Chimica Sinica, 2022, 80(6): 772-780.
[10]	Yuanhao Geng, Xiaoqiu Lin, Yaxin Sun, Huiyu Li, Yue Qin, Congju Li. Preparation of Bimetallic Conductive Metal-organic Framework Material Ni/Co-CAT for Electrocatalytic Oxygen Reduction [J]. Acta Chimica Sinica, 2022, 80(6): 748-755.
[11]	Wenjing Hu, Jiusheng Li. Synthesis of Bis/triaza Crown Ethers and Study of Their Properties as Friction Modifiers^※ [J]. Acta Chimica Sinica, 2022, 80(3): 310-316.
[12]	Zeyang Li, Yusen Yang, Min Wei. Structural Design and Performance of Electrocatalysts for Carbon Dioxide Reduction: A Review [J]. Acta Chimica Sinica, 2022, 80(2): 199-213.
[13]	Xiaohan Yu, Wei Huang, Yanguang Li. Controllable Synthesis and Photocatalytic Applications of Two-dimensional Covalent Organic Frameworks [J]. Acta Chimica Sinica, 2022, 80(11): 1494-1506.
[14]	Jinge Wang, Wei Zhou, Jiayi Li, Yani Ding, Jihui Gao. Recent Advances and Performance Enhancement Mechanisms of Pulsed Electrocatalysis [J]. Acta Chimica Sinica, 2022, 80(11): 1555-1568.
[15]	Xusheng Wang, Xu Yang, Chunhui Chen, Hongfang Li, Yuanbiao Huang, Rong Cao. Graphene Quantum Dots Supported on Fe-based Metal-Organic Frameworks for Efficient Photocatalytic CO₂ Reduction^※ [J]. Acta Chimica Sinica, 2022, 80(1): 22-28.

化学还原法制备纳米铜

Preparation of Nano-particle Copper by Chemical Reduction

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments