Permeation Characteristics of Cobalt(II)-complex Molecularly Imprinted Polymer Membranes

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (18): 1681-1685. Previous Articles Next Articles

Original Articles

钴离子配位分子印迹聚合物膜渗透特性的研究

马向霞¹，李文友*^,1，何锡文¹，张玉奎¹,2

(¹南开大学化学系吸附分离功能高分子材料国家重点实验室天津 300071)
(²中国科学院大连化学物理研究所国家色谱研究分析中心大连 116011)

投稿日期:2004-11-02 修回日期:2005-05-30 发布日期:2010-12-10
通讯作者: 李文友

Permeation Characteristics of Cobalt(II)-complex Molecularly Imprinted Polymer Membranes

MA Xiang-Xia¹, LI Wen-You*^,1, HE Xi-Wen¹, ZHANG Yu-Kui¹,2

(¹Department of Chemistry, State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071)
(²National Chromatographic R. & A. Center, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116011)

Received:2004-11-02 Revised:2005-05-30 Published:2010-12-10
Contact: LI Wen-You

Abstract

Using cobalt-2,2'-bipyridyl complex as template, molecularly imprinted polymer membranes with supporting membranes were synthesized through in-situ polymerization by UV irradiation. The membranes’ surface features were analyzed by scan electron micrography. The imprinted membranes exhibit selective permeation for template in certain cobalt(II) acetate solution through permeation binding experiment. Cation and anion effects on permeation amount of 2,2'-bipyridyl through the molecularly imprinted polymer membrane was investigated respectively. It will be helpful for the development of application of imprinted polymers in sensor device and continuous separation process.

Key words: molecularly imprinted technique, molecularly imprinted membrane, membrane permeation, 2,2'-bipyridyl, cobalt

Cite this article

MA Xiang-Xia, LI Wen-You*^,1, HE Xi-Wen, ZHANG Yu-Kui^1,2. Permeation Characteristics of Cobalt(II)-complex Molecularly Imprinted Polymer Membranes[J]. Acta Chimica Sinica, 2005, 63(18): 1681-1685.

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钴离子配位分子印迹聚合物膜渗透特性的研究

Permeation Characteristics of Cobalt(II)-complex Molecularly Imprinted Polymer Membranes

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