Synthesis, Crystal Structure of Ni(II) Complex with Glucosylamine and Its Catalytic Activity of Hydrolysis of PNPP

Abstract

One complex [Ni(HL)]Cl₂•2H₂O (HL＝1-[(2-aminoethyl)amino]-2-amino-1,2-dideoxy-D-glu- cose) has been synthesized using previously published procedures, and the single crystal of [Ni(HL)]Cl₂• 2H₂O was got. It was characterized by elemental analysis, IR, UV spectra and X-ray diffraction analysis, showing that the complex was in distorted octahedron configuration. Then the catalytic activity of the complex on hydrolysis of p-nitrophenyl picolinate (PNPP) in buffer solution was studied as well.

Key words: metal-saccharide complex, synthesis, crystal structure

Cite this article

ZHANG Wei, JIANG Tao*^,1, REN Su-Mei, GUAN Hua-Shi, YANG Guang-Di². Synthesis, Crystal Structure of Ni(II) Complex with Glucosylamine and Its Catalytic Activity of Hydrolysis of PNPP[J]. Acta Chimica Sinica, 2005, 63(6): 555-558.

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Ni(II)-糖胺金属配合物的合成、晶体结构及催化PNPP水解的活性研究