Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (14): 1385-1388. Previous Articles     Next Articles

Reports

具有二重穿插结构的配位聚合物[Cu(bpy)(OH)]n的合成与结构表征

陈三平, 范广, 高胜利*   

  1. (西北大学化学系 陕西省物理无机化学重点实验室 西安 710069)
  • 投稿日期:2006-12-07 修回日期:2007-01-05 发布日期:2007-07-28
  • 通讯作者: 高胜利

Synthesis and Structural Characterization of a Two-Fold Penetration Coordination Polymer [Cu(bpy)(OH)]n

CHEN San-Ping; FAN Guang; GAO Sheng-Li*   

  1. (Department of Chemistry, Shaanxi Key Laboratory of Physico-inorganic Chemistry, Northwest University, Xi'an 710069)
  • Received:2006-12-07 Revised:2007-01-05 Published:2007-07-28
  • Contact: GAO Sheng-Li

A two-fold penetration coordination polymer [Cu(bpy)(OH)]n (1) (bpy=4,4'-bipyridyl) has been synthesized through hydrothermal reaction and structurally characterized by single crystal X-ray diffraction method. Crystal data: tetragonal, space group I41/acd, a=1.41802(6) nm, b=1.41802(6) nm, c=3.8568(3) nm, β=90.00°, V=7.7552(7) nm3, Z=32, S=1.074, final R indices [I>2σ(I)] R1=0.0345, wR2=0.0767, for all reflections R1=0.0566, wR2=0.0867. In addition, the results of elemental analysis, IR and thermogravimetric analysis were presented.

Key words: hydrothermal reaction, two-fold penetration, coordination polymer, crystal structure