Fabrication of Pricky Star-like Cupric Oxide with Submicrometer Sizes

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (5): 459-464. Previous Articles Next Articles

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亚微米级多刺状星形氧化铜的制备

任崇桂¹,2, 徐建¹, 贾晏金¹, 周丽绘¹, 刘洪来*^,1

(¹华东理工大学化学工程联合国家重点实验室华东理工大学化学系上海 200237)
(²枣庄学院化学化工系枣庄 277146)

投稿日期:2006-05-20 修回日期:2006-08-22 发布日期:2007-03-14
通讯作者: 刘洪来

Fabrication of Pricky Star-like Cupric Oxide with Submicrometer Sizes

REN Chong-Gui¹,2; XU Jian¹; JIA Yan-Jin¹; ZHOU Li-Hui¹; LIU Hong-Lai*^,1

(¹ Department of Chemistry and State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237)
(²Department of Chemistry and Chemical Engineering, Zaozhuang University, Zaozhuang 277146)

Received:2006-05-20 Revised:2006-08-22 Published:2007-03-14
Contact: LIU Hong-Lai

Abstract

Pricky star-like cupric oxide with submicrometer sizes was successfully synthesized by the hydrothermal route using methenamine as precipitant in the presence of cationic gemini surfactant [C₁₆H₃₃(CH₃)₂N^＋(CH₂)₄N^＋(CH₃)₂C₁₆H₃₃]•2Br^－ (16-4-16). The as-prepared products were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscope (TEM). The as-prepared cupric oxide had monoclinic structure. The effects of concentrations of gemini surfactant, reaction temperature and reagents on the sample morphology were investigated.

Key words: star-like cupric oxide, gemini surfactant, shape control, hydrothermal synthesis

Cite this article

REN Chong-Gui^1,2; XU Jian; JIA Yan-Jin; ZHOU Li-Hui; LIU Hong-Lai*^,1. Fabrication of Pricky Star-like Cupric Oxide with Submicrometer Sizes[J]. Acta Chimica Sinica, 2007, 65(5): 459-464.

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亚微米级多刺状星形氧化铜的制备

Fabrication of Pricky Star-like Cupric Oxide with Submicrometer Sizes

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