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Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (18): 2065-2069. Previous Articles     Next Articles

Original Articles

N,N’-二(2-吡啶基)-1,6,7,12-四(4-叔丁基苯氧基)-3,4:9,10-苝酰亚胺的合成、表征及性能研究

王洪宇 彭 波 韦 玮*

  

  1. (复旦大学光科学与工程系 先进光子学材料与器件国家重点实验室 上海 200433)
  • 投稿日期:2008-03-09 修回日期:2008-05-08 发布日期:2008-09-28
  • 通讯作者: 韦 玮

Synthesis, Characterization and Properties of N,N’-Bi(2-pyridyl)-1,6,7,12-terta(4-tert-butylphenoxy)-perylene- 3,4:9,10-tetracarboxylic Diimide

WANG, Hong-Yu PENG, Bo WEI, Wei*   

  1. (State Key Laboratory for Advanced Photonic Materials & Devices, Department of Optical Science and Engineering,
    Fudan University, Shanghai 200433)
  • Received:2008-03-09 Revised:2008-05-08 Published:2008-09-28
  • Contact: WEI, Wei

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The synthetic methods of N,N’-bi(2-pyridyl)-1,6,7,12-terta(4-tert-butylphenoxy)-perylene-3,4: 9,10-tetracarboxylic diimide were optimized. A simple and effective synthetic method to substitute at both imide and bay positions was gained. The structure was investigated. And its optical and electrochemical properties were studied in both solution and thin films. And the theoretical calculations were also carried out regarding the energy levels and electron distribution.

Key words: perylene diimide, synthesis, optoelectronic property, molecular simulation