Resonance Rayleigh Scattering of Palladium(II)-tartrazine-ionic Liquid System and Its Analytical Application

Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (04): 334-338. Previous Articles Next Articles

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钯(II)-柠檬黄-离子液体三元络合体系的共振瑞利散射光谱及其分析应用研究

陈智栋¹^{,2，肖莹¹^{,2，曾延波¹，李蕾*^{,1,2，路齐英¹^{,2，王伟娟¹^,2}}}}

(¹嘉兴学院生物与化学工程学院嘉兴 314001)
(²江苏工业学院化学化工学院常州 213016)

投稿日期:2009-05-30 修回日期:2009-09-18 发布日期:2010-02-28
通讯作者: 李蕾 E-mail:lileichem@yahoo.com.cn
基金资助:
浙江省科技计划重点项目（No.2007C23071）；浙江省自然科学基金（No.Y4080252）资助项目

Resonance Rayleigh Scattering of Palladium(II)-tartrazine-ionic Liquid System and Its Analytical Application

Chen Zhidong¹^{,2 Xiao Ying¹^{,2 Zeng Yanbo¹ Li Lei*^{,1,2 Lu Qiying¹^{,2 Wang Weijuan¹^,2}}}}

(¹ College of Biology and Chemical Engineering, Jiaxing University, Jiaxing 314001)
(² College of Chemistry and Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016)

Received:2009-05-30 Revised:2009-09-18 Published:2010-02-28
Contact: LI Lei E-mail:lileichem@yahoo.com.cn

Abstract

In pH 2.0～6.0 Britton-Robinson solution, palladium(II) was reacted with tartrazine to form a complex anion, which was further reacted with ionic liquid to form an anion-association complex, resulting in the change of the resonance Rayleigh scattering (RRS), and its maximum RRS peak was located at 458 nm. The RRS intensity is proportional to the concentration of tartrazine in the range of 0.043～0.860 μg/mL. The method shows high sensitivity and good selectivity, with the detection limit for tartrazine being 5.5 ng/mL (n＝11). The method can be applied to the determination of tartrazine in beverage.

Key words: tartrazine, resonance Rayleigh scattering, palladium(II), ionic liquid, beverage

Cite this article

CHEN Zhi-Dong, XIAO Ying, CENG Yan-Bei, LI Lei, LU Ji-Yang, WANG Wei-Juan. Resonance Rayleigh Scattering of Palladium(II)-tartrazine-ionic Liquid System and Its Analytical Application[J]. Acta Chimica Sinica, 2010, 68(04): 334-338.

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钯(II)-柠檬黄-离子液体三元络合体系的共振瑞利散射光谱及其分析应用研究

Resonance Rayleigh Scattering of Palladium(II)-tartrazine-ionic Liquid System and Its Analytical Application

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