Synthesis of Bipolar-Transporting Materials Containing Carbazole and Aryl Oxadiazole Groups Bridged with 1,2-Ethylene and Their Optoelectronic Properties

Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (07): 661-666. Previous Articles Next Articles

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1,2-亚乙基桥联咔唑和芳基噁二唑的双极传输材料的合成及光电性能研究

高健，刘煜*，谭华，李亮，曹韵波，梁爱辉，朱卫国

(湘潭大学化学学院环境友好化学与应用省部共建教育部重点实验室湘潭 411105)

投稿日期:2009-07-21 修回日期:2009-10-30 发布日期:2010-04-14
通讯作者: 朱卫国 E-mail:zhuwg18@126.com
基金资助:
国家自然科学基金(No. 20772101)；高等学校博士学科点新教师基金(No. 200805301013)

Synthesis of Bipolar-Transporting Materials Containing Carbazole and Aryl Oxadiazole Groups Bridged with 1,2-Ethylene and Their Optoelectronic Properties

Gao Jian Liu Yu* Tan Hua Li Liang Cao Yunbo Liang Aihui Zhu Weiguo*

(Key Laboratory of Environment-friendly Chemistry and Application Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105)

Received:2009-07-21 Revised:2009-10-30 Published:2010-04-14
Contact: Zhu Weiguo E-mail:zhuwg18@126.com

Abstract

Three bipolar-transporting materials containing carbazole and aryl oxadiazole groups bridged with 1,2-ethylene were synthesized and characterized by ¹H NMR, ¹³C NMR and elemental analysis. Their UV-Vis absorption and photoluminescent properties, as well as their electrochemical properties and thermal stability were also studied. The results show that this class of bipolar-transporting materials displayed UV-Vis absorption and photoluminescent properties of both carbazole and aryl oxadiazole groups, and their thermal decomposing temperatures are over 340 ℃. Compared with those bipolar-transporting materials containing carbazole and aryl oxadiazole groups connected with conjugated groups, these bipolar-trans- porting materials here presented high HOMO and LUMO energy levels and thermal stability.

Key words: bipolar-transporting material, carbazole, oxadiazole, synthesis, optoelectronic property

CLC Number:

O627.8

Cite this article

GAO Jian, LIU Yu, TAN Hua, LI Liang, CAO Yun-Bei, LIANG Ai-Hui, SHU Wei-Guo. Synthesis of Bipolar-Transporting Materials Containing Carbazole and Aryl Oxadiazole Groups Bridged with 1,2-Ethylene and Their Optoelectronic Properties[J]. Acta Chimica Sinica, 2010, 68(07): 661-666.

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1,2-亚乙基桥联咔唑和芳基噁二唑的双极传输材料的合成及光电性能研究

Synthesis of Bipolar-Transporting Materials Containing Carbazole and Aryl Oxadiazole Groups Bridged with 1,2-Ethylene and Their Optoelectronic Properties

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