Preparation and Properties of γ-MnO2 Nanotubes as Electrode Materials of Supercapacitor

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (05): 503-507. Next Articles

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超级电容器电极材料γ-MnO₂纳米管的制备及性能

陈智栋^1,2，高兰^1，曹剑瑜^1，王文昌^1，许娟^*,1,2

(¹常州大学化学化工学院常州 213164)
(²常州江工阔智有限公司常州 213164)

投稿日期:2010-08-07 修回日期:2010-09-18 发布日期:2010-11-11
通讯作者: 许娟 E-mail:cjytion3@163.com
基金资助:
石墨烯负载纳米金属修饰的LiBH4储氢性能及催化机制研究;基于氧化铝摸板(AAO)技术的纳米电源的制备及其电化学性能研究

Preparation and Properties of γ-MnO₂ Nanotubes as Electrode Materials of Supercapacitor

Chen Zhidong^1,2 Gao Lan¹ Cao Jianyu¹ Wang Wenchang¹ Xu Juan^*,1,2

(¹Department of Chemical Engineering and Technology, Changzhou University, Changzhou 213164)
(²Changzhou Jiangsu Polytechnic University Qualtec Co. Ltd., Changzhou 213164)

Received:2010-08-07 Revised:2010-09-18 Published:2010-11-11
Contact: Juan Xu E-mail:cjytion3@163.com

Abstract

γ-MnO₂ nanotubes have been successfully synthesized by chemically depositing manganese hydroxide in anodic aluminum oxide (AAO) templates and thermally annealing at 500 ℃. The synthesized nanotubes have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen adsorption-desorption isotherm analysis. The electrochemical capacitance behavior of the γ-MnO₂ nanotubes electrode was investigated by cyclic voltammetry and galvanostatic charge-discharge studies in 1 mol/L Na₂SO₄ solution. The electrochemical data demonstrate that the γ-MnO₂ nanotubes display good capacitive behavior with a high specific capacitance of 566 F/g at a current density of 100 mA/g and a good specific capacitance retention of ca. 90% after 1000 continuous charge-discharge cycles, indicating that the γ-MnO₂ nanotubes can be promising electroactive materials for supercapacitor.

Key words: γ-MnO₂ nanotubes, AAO template, supercapacitor

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CHEN Zhi-Dong, GAO Lan, CAO Jian-Yu, WANG Wen-Chang, XU Juan. Preparation and Properties of γ-MnO₂ Nanotubes as Electrode Materials of Supercapacitor[J]. Acta Chimica Sinica, 2011, 69(05): 503-507.

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超级电容器电极材料γ-MnO₂纳米管的制备及性能

Preparation and Properties of γ-MnO₂ Nanotubes as Electrode Materials of Supercapacitor

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超级电容器电极材料γ-MnO2纳米管的制备及性能