Synthesis and crystal structure of bis-PPh3-substituted Fe-S cluster complex (μ-i-C3H7S)-(μ-PhCh2S)Fe2 (CO)4(PPh3)2

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (10): 984-990. Previous Articles Next Articles

Original Articles

双三苯膦铁硫原子簇配合物(μ-i-C3H7S)(μ-PhCH2S)-Fe2(CO)4(PPh3)2的合成及晶体结构

宋礼成;胡青眉;王如骥;王宏根

南开大学化学系;南开大学测试计算中心

发布日期:1988-10-15

Synthesis and crystal structure of bis-PPh3-substituted Fe-S cluster complex (μ-i-C3H7S)-(μ-PhCh2S)Fe2 (CO)4(PPh3)2

SONG LICHENG;HU QINGMEI;WANG RUJI;WANG HONGGEN

Published:1988-10-15

Abstract

Reaction of (m-Me2CHS)(m-PhCH2S)Fe2(CO)6 with excess PPh3 in boiling toluene for 6 h gave (m-Me2CHS)(m-PhCH2S)Fe2(CO)4(PPh3)2 (I). The crystal of I is triclinic, P1, with a 10.268(4), b 20.289(1), c 22.799(5) ? a 94.73(1), b 102.98(2), g 89.93(1)? Z = 4, R = 0.059 and Rw = 0.068. The cluster core of I consists of 2 Fe and 2 S atoms and has a butterfly structure. Two PPh3 ligands bonded to 2 Fe atoms are at the positions trans to Fe-Fe bent bond; Me2CH and PhCH2 groups are attached to different S atoms by equatorial bonds.

Key words: CRYSTAL STRUCTURE, IRON COMPLEX, CARBONYL COMPLEX, TRIPHENYLPHOSPHINE, CLUSTER COMPOUND, SULFIDE COMPLEX

CLC Number:

O611.662

Cite this article

SONG LICHENG;HU QINGMEI;WANG RUJI;WANG HONGGEN. Synthesis and crystal structure of bis-PPh3-substituted Fe-S cluster complex (μ-i-C3H7S)-(μ-PhCh2S)Fe2 (CO)4(PPh3)2[J]. Acta Chimica Sinica, 1988, 46(10): 984-990.

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双三苯膦铁硫原子簇配合物(μ-i-C3H7S)(μ-PhCH2S)-Fe2(CO)4(PPh3)2的合成及晶体结构

Synthesis and crystal structure of bis-PPh3-substituted Fe-S cluster complex (μ-i-C3H7S)-(μ-PhCh2S)Fe2 (CO)4(PPh3)2

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