Acta Chimica Sinica ›› 2009, Vol. 67 ›› Issue (3): 208-212. Previous Articles     Next Articles

Original Articles

模板法制备的有序介孔Co3O4的电化学电容行为

吴 雯 王永刚 李 峰 夏永姚*

  

  1. (复旦大学化学系 上海 200433)

  • 投稿日期:2007-12-03 修回日期:2008-10-07 发布日期:2009-02-14
  • 通讯作者: 夏永姚

Electrochemical Capacitance Performance of Ordered Mesoporous Co3O4 Synthesized by Template Method

Wu, Wen Wang, Yonggang Li, Feng Xia, Yongyao*   

  1. (Chemistry Department and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433)
  • Received:2007-12-03 Revised:2008-10-07 Published:2009-02-14
  • Contact: Xia, Yongyao

Ordered crystallized Co3O4 nanoarrays were synthesized by replicating mesoporous silica template and its electrochemical capacitance performance was evaluated in 6 mol/L KOH electrolyte solution. Electrochemical tests results indicated that the ordered mesoporous structure of Co3O4 nanoarrays provide a capacitance of about 250 F/g, approximately four times larger than that of Co3O4 prepared by direct calcining Co(NO3)•6H2O at 550 ℃ and also exhibits a good rate capability. This is due to that the well ordered mesoporous structure provide large specific surface area and facilitates the fast transport of the electrolyte.

Key words: supercapacitor, Co3O4, mesoporous structure