Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1- oxime

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (6): 1058-1064. Previous Articles Next Articles

Original Articles

线型1,2-邻二萘醌-1-肟(1-nqo)钌配合物的合成

刘晓霞;孙克;黄永德;朱建军;张宝砚

东北大学化学系,沈阳(110004);香港大学化学系.香港

发布日期:2002-06-15

Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1- oxime

Liu Xiaoxia;Sun Ke;Wong Wingtak;Niu Jianjun;Zhang Baoyan

Department of Chemistry, Northeastern University,Shenyang(110004);Department of Chemistry, The University of Hong Kong.Hong Kong

Published:2002-06-15

Abstract

By decarbonylated substitution reactions, rod-like ruthenium complexes of 1,2-naphthoquinone-1-oxime (1-nqo) are synthesized as trans-, cis- and cis-, cis-[Ru(1-nqo)_2(CO)(spy)] (3) and (4) which containing C_(16) long alkyl chains in the molecules, cis-, cis-[Ru(1- nqo)_2(CO)(opy)] (5) and trans-, trans-[Ru(1-nqo)_2(opy)_2] (6) which containing C_(18) long alkyl chains in the molecules. The complexes are characterized by IR, FAB MS, - ~1H-~1H COSY NMR and UV-visible spectra.

Key words: RUTHENIUM COMPLEX, NAPHTHOQUINONE, CARBONYL COMPOUNDS, SUBSTITUTION REACTION, OXIME, IR, 1HNMR

CLC Number:

O621

Cite this article

Liu Xiaoxia;Sun Ke;Wong Wingtak;Niu Jianjun;Zhang Baoyan. Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1- oxime[J]. Acta Chimica Sinica, 2002, 60(6): 1058-1064.

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线型1,2-邻二萘醌-1-肟(1-nqo)钌配合物的合成

Synthesis of Rod-like Ruthenium Complexes of 1,2-Naphthoquinone-1- oxime

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