Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (11): 1809-1812. Previous Articles     Next Articles

Original Articles

对位取代二苯乙烯衍生物的合成和非线性光学性质

延云兴;陶绪堂;杨家祥;王东;于晓强;赵显;蒋民华   

  1. 山东大学
  • 发布日期:2003-11-15

Synthesis and Nonlinear Optical Properties of New p-Substituted Stilbenes

Tan Yunxing;Tao Xutang;Yang Jiaxiang;Wang Dong;Yu Xiaoqiang;Zhao Xian;Jiang Minhua   

  1. State Key Laboratory of Crystal Materials, Shandong University
  • Published:2003-11-15

Three new chromophores and 4-nitro-benzoic acid 2-( |4-[2-(4- dimethylamino-phenyl)-vinyl]-phenyl|-ethylamino)-ethyl ester (DMANHAS) have been synthesized and the structures have been characterized by 'H NMR, IR and elemental analyses. Linear absorption, single- photon induced fluorescence and two-photon induced fluorescence are experimentally studied. When pumped with 800 nm laser irradiation, 2-( |4-[2-(4-dimethylamino-phenyl)-vinyl ] -phenyl | - ethylamino )-ethanol (DMAHAS ) and 2-(14-[ 2-( 4-diethylamino-phenyl) - vinyl ]-phenyl (-ethylamino)-ethanol (DEAHAS) show strong two-photon induced blue fluorescence at 436 and 440 nm respectively, while DMANHAS and 4-nit.ro-benzoic acid 2-( |4-[2-(4-diethylamino-phenyl)- vinyl]-phenyl(-ethylamino)-ethyl ester (DEANHAS) exhibit no fluorescence.

Key words: STYRENE P, NON LINEAR OPTICS, UV, FLUOROSPECTROPHOTOMETRY, UP-CONVERESION LUMINESCENCE

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