Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (9): 1484-1487. Previous Articles     Next Articles

Original Articles

TiO_2纳米粒子的表面修饰研究

李宗威;朱永法   

  1. 清华大学化学系
  • 发布日期:2003-09-15

Study on the Surface-modification of TiO_2 Nanoparticles

Li Zongwei;Zhu Yongfa   

  1. Department of Chemistry, Tsinghua University
  • Published:2003-09-15

TiO2 nanoparticles modified by oleic acid ( OA) were prepared using surface-modification method. Infrared spectroscopy (IR), transmission electron microscopy (TEM) and X-ray photoelectron spectra (XPS) were used to investigate' the structure of the modified TiO_2 nanopartieles. Effects of OA concentration on coverage and dispersion in oil were also studied. The optimal proportion of OA to TiO_2 was established. The results indicate that the oleic acid is bonded to the surface of TiO_2 nanoparticles. The OA-modified TiO_2 nanoparticles have good dispersive capacity in organic solvent and mineral oil. An esterification mechanism for the surface-modification is proposed.

Key words: OLEIC ACID, TITANIUM OXIDE, IR, TEM, XPS, STRUCTURE CHARACTERISTICS

CLC Number: