Synthesis and crystal structure of PdMo(μ-Ph~2Ppy)~2(μ -CO)(CO)~2I~2.0.5CH~2Cl~2

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (11): 1053-1058. Previous Articles Next Articles

Original Articles

异双核化合物PdMo(μ-Ph~2Ppy)~2(μ-CO)(CO)~2I~2.0.5CH~2Cl~2的合成和晶体结构

张正之;席华平;王宏根;王如骥

南开大学元素有机化学研究所;南开大学中心实验室

发布日期:1993-11-15

Synthesis and crystal structure of PdMo(μ-Ph~2Ppy)~2(μ -CO)(CO)~2I~2.0.5CH~2Cl~2

ZHANG ZHENGZHI;XI HUAPING;WANG HONGGEN;WANG RUJI

Published:1993-11-15

Abstract

A new complex containing a Pd-Mo bond, PdMo(m-Ph2Ppy)2(m-CO)(CO)2I3.0.5CH2Cl2 (Ph2Ppy = 2-(diphenylphosphino)pyridine) was synthesized and characterized by elemental anal., IR, 31P NMR spectroscopies. The structure of the complex was determine by x-ray single crystal diffraction anal. The mol. crystd. in the triclinic space group P1 with a 0.9500(2), b 1.1302(2), c 1.993(1) nm, a 102.82(3), b 101.21(3), g 94.57(2)? V = 2.029(2) nm3, Z = 2, F(000) = 1036, m = 23.6 cm-1, R = 0.064 for 3492 unique reflections [I ?3s(I)]. The Pd atom is d9 5-coordinated and the Mo atom is d5 7-coordinated. Both metal atoms possess the +1 formal oxidation state. The mol. is chiral and belongs to the C1 point group.

Key words: PYRIDINE P, CRYSTAL STRUCTURE, PHOSPHINE, MOLYBDENUM COMPLEX, DINUCLEAR COMPLEX, PALLADIUM COMPLEX

CLC Number:

O627

Cite this article

ZHANG ZHENGZHI;XI HUAPING;WANG HONGGEN;WANG RUJI. Synthesis and crystal structure of PdMo(μ-Ph~2Ppy)~2(μ -CO)(CO)~2I~2.0.5CH~2Cl~2[J]. Acta Chimica Sinica, 1993, 51(11): 1053-1058.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Yandong Zhang, Shoufei Zhu. Perspective for Phosphine Ligands with Cyclopropane Backbone^★ [J]. Acta Chimica Sinica, 2023, 81(7): 777-783.
[3]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[4]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[5]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[6]	Yunfang Xu, Yang Li, Zitong Fu, Shaoyan Lin, Jie Zhu, Lei Wu. Palladium-catalyzed Stereoselective Synthesis of (Z)-[3]Dendralenes [J]. Acta Chimica Sinica, 2022, 80(10): 1369-1375.
[7]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[8]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[9]	Zhu Ren-Yi, Liao Kui, Yu Jin-Sheng, Zhou Jian. Recent Advances in Catalytic Asymmetric Synthesis of P-Chiral Phosphine Oxides [J]. Acta Chimica Sinica, 2020, 78(3): 193-216.
[10]	Zhang Ronghua, Xu Bing, Zhang Zhanming, Zhang Junliang. Ming-Phos/Copper(I)-Catalyzed Asymmetric[3+2] Cycloaddition of Azomethine Ylides with Nitroalkenes [J]. Acta Chimica Sinica, 2020, 78(3): 245-249.
[11]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[12]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[13]	Zhang Yongling, Wang Min, Cao Peng, Liao Jian. Copper-Catalyzed Enantioselective Aminoboration of Styrenes with Chiral Sulfoxide Phosphine Ligand [J]. Acta Chim. Sinica, 2017, 75(8): 794-797.
[14]	Li Ran, Xu Wenyuan, Zhao Jinqin, Yu Xin, Wang Wenguang, Tung Chen-Ho. Azo-bridged New Diiron Carbonyl Complex: Synthesis of Fe₂(NR)₂-(CO)_6-x(PR₃)_x and the Derivatives [J]. Acta Chim. Sinica, 2017, 75(1): 92-98.
[15]	Yang Lijun, Ma Junan. New Advances on Nucleophilic Phosphine-Triggered Annulation Reactions of Allenoates [J]. Acta Chim. Sinica, 2016, 74(2): 130-148.

异双核化合物PdMo(μ-Ph~2Ppy)~2(μ-CO)(CO)~2I~2.0.5CH~2Cl~2的合成和晶体结构

Synthesis and crystal structure of PdMo(μ-Ph~2Ppy)~2(μ -CO)(CO)~2I~2.0.5CH~2Cl~2

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments