Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (12): 1201-1205. Previous Articles    

Original Articles

逐级电子转移过程的0.5次微分电分析法

薛永军;袁倬斌   

  1. 中国科学技术大学研究生院
  • 发布日期:1989-12-15

Half-differential polarography with multistep reversible charge transfers

XUE YONGJUN;YUAN ZHUOBIN   

  • Published:1989-12-15

The theory of 0.5th order differential polarog. for multistep reversible charge transfers is proposed, and a theor. polarogram was computer simulated. The effect of both the standard potential separation (DE? and the no. of electrons on polarograms is discussed. The reduction of Cu(II) in 0.10M NH4Cl-NH4OH was selected to test the theory, and reasonable agreement between theory and experiment was obtained.

Key words: VOLTAMMETRY, POLAROGRAPHIC ANALYSIS, ELECTRON TRANSFER, ELECTROCHEMICAL ANALYSIS, CONVOLUTION

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