Solvothermal Synthesis and Characterization of an Open-Framework [Me4N]2HgGe4S10

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (5): 371-374. Previous Articles Next Articles

Original Articles

微孔[Me₄N]₂HgGe₄S₁₀的溶剂热合成与表征

朱阳春¹，白音孟和¹，刘新¹，贾翠英¹，刘晓阳²，安永林*^,1

(¹大连理工大学化学系大连116024)
(²吉林大学无机合成与制备国家重点实验室长春130012)

投稿日期:2005-05-18 修回日期:2005-11-07 发布日期:2006-03-15
通讯作者: 安永林

Solvothermal Synthesis and Characterization of an Open-Framework [Me₄N]₂HgGe₄S₁₀

ZHU Yang-Chun¹, BAIYIN Meng-He¹, LIU Xin¹, JIA Cui-Ying¹, LIU Xiao-Yang², AN Yong-Lin*^,1

(¹ Department of Chemistry, Dalian University of Technology, Dalian 116024)
(² Key Laboratory of Inorganic Synthesis and Preparation, Jilin University, Changchun 130012)

Received:2005-05-18 Revised:2005-11-07 Published:2006-03-15
Contact: AN Yong-Lin

Abstract

An open-framework [Me₄N]₂HgGe₄S₁₀ (1) was solvothermally synthesized and characterized by single crystal diffraction, IR and DSC-TG techniques. Compound 1 was built up from supertetrahedra and HgS₄, and has 1D channels with pore sizes of 0.94 nm×0.65 nm along direction a or b. TG-DSC results indicated that 1 has a good thermal stability in a nitrogen. Crystal data for 1: M_r＝957.55, space group I-4, a＝0.92687(8) nm, c＝1.43739(12) nm, V＝1.23484(18) nm³, Z＝2, Mo Kα λ＝0.071073 nm, R₁＝0.057, wR₂＝0.1374 for 906 reflections with I＞2σ(I).

Key words: solvothermal synthesis, crystal structure, open-framework, thermal stability

Cite this article

ZHU Yang-Chun, BAIYIN Meng-He, LIU Xin, JIA Cui-Ying, LIU Xiao-Yang², AN Yong-Lin*^,1. Solvothermal Synthesis and Characterization of an Open-Framework [Me₄N]₂HgGe₄S₁₀[J]. Acta Chimica Sinica, 2006, 64(5): 371-374.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[3]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[4]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[5]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[6]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[7]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[8]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[9]	Dong Lu, Zheng Chunying, Zhou Pei, Shi Rufei, Li Hui. Advances in Crystallography of Coordination Complexes on Main Group Metals with Amino Acid Ligands [J]. Acta Chimica Sinica, 2014, 72(9): 981-1000.
[10]	Ni Chunyan, Chen Yang, Li Duanxiu, Ren Zhigang, Li Hongxi, Sun Zhenrong, Lang Jianping. Halide-Directed Synthesis of Coordination Polymers [Hg₂X₄(ppt)]_n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties [J]. Acta Chimica Sinica, 2013, 71(06): 906-912.
[11]	Han Cong, Xu Zhe, Diao Chunhua, Chen Xin, Liu Jing, Guo Minjie, Fan Zhi. Self-assembly Behavior of Interlocked Helical Supramolecule of Cyclodextrin Modified by 2-Furanmethanethiol [J]. Acta Chimica Sinica, 2013, 71(03): 439-442.
[12]	Duan Xianying, Guo Libing, Wang Jianli. A Good Proton-conductive Polyoxometalate Complex {[Co(H₂O)₈][H(H₂O)₃](HINO)₄(PW₁₂O₄₀)}_n: Synthesis, Crystal Structure and Properties [J]. Acta Chimica Sinica, 2013, 71(01): 107-113.
[13]	Guo Qiong, Li Lianzhi, Dong Jianfang, Liu Hongyan, Xue Zechun, Xu Tao . Synthesis, Crystal Structure and Interactions with DNA and BSA of a Oxovanadium(IV) Complex [VO(o-Van-Asn)(Phen)]?1.5CH₃OH [J]. Acta Chimica Sinica, 2012, 70(15): 1617-1624.
[14]	Lu Yanmei, Ou Zhibin, Hu Wei, Le Xueyi. Structure, Antibacterial Activities and DNA Cleavage of a Copper(II) Complex with 2-(2'-Pyridyl)benzimidazole and L-Alaninate [J]. Acta Chimica Sinica, 2012, 70(08): 973-979.
[15]	Lu Dongfei, Di Youying, Dou Jianmin. Synthesis, Crystal Structure and Low-temperature Heat Capacities of Bis(n-undecylammonium)tetrachlorocadmiumate [J]. Acta Chimica Sinica, 2012, 70(07): 889-896 .

微孔[Me₄N]₂HgGe₄S₁₀的溶剂热合成与表征

Solvothermal Synthesis and Characterization of an Open-Framework [Me₄N]₂HgGe₄S₁₀

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

微孔[Me4N]2HgGe4S10的溶剂热合成与表征