The spectra of the π-π charge-transfer complexes and the method of their deconvolution

Acta Chimica Sinica ›› 1983, Vol. 41 ›› Issue (4): 289-296. Next Articles

Original Articles

丌-丌电荷转移复合物的光谱及其图解方法的探讨

刘昌炎;胡日恒

中国科学院化学研究所

发布日期:1983-04-15

The spectra of the π-π charge-transfer complexes and the method of their deconvolution

LIU CHANGYAN;HU RIHENG

Published:1983-04-15

Abstract

In this report, a method for deconvoluting the multi-band spectra of charge-transfer complex is presented and a relation between double-bands is proposed. 49 such spectra in which double-bands appear are calculated. It has been found that the deviation between the calculated and the measured values is less than 3%. The scheme can be extended to deconvolute the CT peaks are used to evaluate the electron affinities of these acceptors. But, the scheme can be used to the π-π charge-transfer complexes.

Key words: DETERMINATION, DECOMPOSITION, CHARGE TRANSFER COMPLEX, SPECTRA

CLC Number:

O657

Cite this article

LIU CHANGYAN;HU RIHENG. The spectra of the π-π charge-transfer complexes and the method of their deconvolution[J]. Acta Chimica Sinica, 1983, 41(4): 289-296.

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丌-丌电荷转移复合物的光谱及其图解方法的探讨

The spectra of the π-π charge-transfer complexes and the method of their deconvolution

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