Synthesis and crystal structure of a novel  one-dimensional cyano- bridged chain complex  [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n

Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (12): 1636-1640. Previous Articles Next Articles

Original Articles

一维链状氰根桥联配合物 [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n的合成和晶体结构

闫冰;陈志达;王诗玺

北京大学化学与分子工程学院;北京大学稀土材料化学及应用国家重点实验室. 北京;北京大学-香港大学稀土材料与生物无机联合实验室;济宁师范专科学校化学系

发布日期:2000-12-15

Synthesis and crystal structure of a novel one-dimensional cyano- bridged chain complex [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n

Yan Bing;Chen Zhida;Wang Shixi

Published:2000-12-15

Abstract

Using K~3Fe(CN)~6, N,N-dimethylacetamide (DMA) and Sm(NO~3)~3·6H~2O, the title complex [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n has been synthesized and characterized with elemental analysis, IR spectra and X-ray crystal structure. The complex crystallizes in the monoclinic P2~1/c space group, with lattice parameters a=1.02744(4) nm, b=1.6732 (2) nm, c=1.7323(2) nm, β=97.385(3)°, Z=4, R~1=0.0412.

Key words: SAMARIUM COMPLEX, CRYSTAL STRUCTURE, ACETAMIDE P, ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, FERRICYANIDE

CLC Number:

O611.662

Cite this article

Yan Bing;Chen Zhida;Wang Shixi. Synthesis and crystal structure of a novel one-dimensional cyano- bridged chain complex [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n[J]. Acta Chimica Sinica, 2000, 58(12): 1636-1640.

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一维链状氰根桥联配合物 [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n的合成和晶体结构

Synthesis and crystal structure of a novel one-dimensional cyano- bridged chain complex [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n

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一维链状氰根桥联配合物 [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n的合成和晶 体结构

Synthesis and crystal structure of a novel one-dimensional cyano- bridged chain complex [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n

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Abstract

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一维链状氰根桥联配合物 [Sm(DMA)~2(H~2O)~4Fe(CN)~6·5H~2O]~n的合成和晶体结构