Synthesis of alkylformamide catalyzed by organic  Au(Ⅰ) complexes

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (6): 979-981. Previous Articles Next Articles

Original Articles

有机金配合物催化羰化胺制甲酰胺

石峰;邓友全

中国科学院兰州化学物理研究所.兰州(730000);羰基合成与选择氧化国家重点实验室

发布日期:2001-06-15

Synthesis of alkylformamide catalyzed by organic Au(Ⅰ) complexes

Shi Feng;Deng Youquan

Lanzhou Inst Chem Phys, CAS.Lanzhou(730000)

Published:2001-06-15

Abstract

The synthesis of alkyl formamide catalyzed by organc Au(Ⅰ) complexes was firstly proceeded in the presence of carbon monoxide, dixygen and appropriate solutions with high conversion and selectivity. The results showed that the selectivity for diformamide could be greatly enhanced in the presence of small amount of dioxygen. The results obtained by using organic Au(Ⅰ) complexes as the catalysts were comparable to the results obtained by using organic Pd (Ⅱ) as the catalyst.

Key words: CATALYTIC REACTION, ALIPHATIC AMINES, CARBON MONOXIDE, FORMAMIDE, CARBONYLATION, GOLD COMPLEX

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Cite this article

Shi Feng;Deng Youquan. Synthesis of alkylformamide catalyzed by organic Au(Ⅰ) complexes[J]. Acta Chimica Sinica, 2001, 59(6): 979-981.

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有机金配合物催化羰化胺制甲酰胺

Synthesis of alkylformamide catalyzed by organic Au(Ⅰ) complexes

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