Study on the chemiluminescent characteristics of  mulitbipyridine ruthenium (Ⅱ) complexes

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (9): 1513-1518. Previous Articles Next Articles

Original Articles

多吡啶钌(Ⅱ)配合物化学发光性质研究

韩鹤友;何治柯;曾云鹗

中国科学技术大学化学系.合肥(230026);武汉大学化学系.武汉(430072)

发布日期:2001-09-15

Study on the chemiluminescent characteristics of mulitbipyridine ruthenium (Ⅱ) complexes

Han Heyou;He Zhike;Zeng Yune

Univ Sci & Technol China, Dept Chem.Hefei(230026);Wuhan Univ, Dept Chem.Wuhan(430072)

Published:2001-09-15

Abstract

The chemiluminescent characteristics of Ru(bpy)3^2+, Ru(bpy)2(dppx) ^2+, Ru(bpy)2(dppz)^2+, Ru(phen)3^2+, Ru(phen)2(dppx)^2+ and Ru(phen)2 (dppz)^2+ have been studied in detail. It is found that Ru(bpy)3^2+ and Ru(phen)3^2+ have better chemiluminescence activities than others. A mechanism of luminescence of these ruthenium complexes is proposed. The results obtained may be useful as theory references for applications of ruthenium (Ⅱ) complexes in many chemiluminescence systems.

Key words: CHEMILUMINESSENCE, RUTHENIUM COMPLEX, PYRIDINE P, PHENANTHROLINE

CLC Number:

O644

Cite this article

Han Heyou;He Zhike;Zeng Yune. Study on the chemiluminescent characteristics of mulitbipyridine ruthenium (Ⅱ) complexes[J]. Acta Chimica Sinica, 2001, 59(9): 1513-1518.

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多吡啶钌(Ⅱ)配合物化学发光性质研究

Study on the chemiluminescent characteristics of mulitbipyridine ruthenium (Ⅱ) complexes

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