Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (16): 1869-1872. Previous Articles     Next Articles

Original Articles

PbS量子点的一步合成法及其光学性能

赵旭升* 干建群 刘光华 陈爱民

  

  1. (中国科学院广州化学研究所 广州 510650)

  • 投稿日期:2007-12-10 修回日期:2008-03-03 发布日期:2008-08-28
  • 通讯作者: 赵旭升

One-step Synthesis and Optical Properties of PbS Quantum Dots

ZHAO, Xu-Sheng* GAN, Jian-Qun LIU, Guang-Hua CHEN, Ai-Min   

  1. (Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650)
  • Received:2007-12-10 Revised:2008-03-03 Published:2008-08-28
  • Contact: ZHAO, Xu-Sheng

Size-tunable PbS quantum dots were synthesized using 1-thioglycerol and dithioglycerol as stabilizers via a facile one-step synthetic method. Instead of the traditional organometallic route, in which toxic precursors or solvents might be used, the wet chemical approach demonstrated in this paper is superior in terms of simplicity, use of nontoxic materials, mild synthetic condition and good reproducibility. The resultant PbS quantum dots are monodispersed with particle size ranging from 3 to 5 nanometers. Photoluminescence quantum efficiency of the as-synthetic quantum dots is up to 11.8% and can be maintained by 80% within five weeks with additional capping agents introduced into the storage vessel.

Key words: PbS quantum dot, wet chemical synthesis, photoluminescence, photoluminescence quantum efficiency