Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process

doi:10.6023/A20040134

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (5): 407-411.DOI: 10.6023/A20040134 Previous Articles Next Articles

Communication

通过赝反伽伐尼反应实现金纳米粒子模块替换

金凤鸣^a,b,c, 董宏伟^a,b,c, 赵燕^a,b,c, 庄胜利^a,c, 廖玲文^a,c, 闫楠^a,c, 古万苗^a,b,c, 查珺^a,b,c, 袁金云^d, 李进^e, 邓海腾^f, 甘自保^a,c, 杨金龙^d, 伍志鲲^a,c

a 中国科学院固体物理研究所中国科学院材料物理重点实验室安徽省纳米材料与技术重点实验室中国科学院纳米卓越中心合肥 230031;
b 中国科学技术大学合肥 230026;
c 安徽大学物质科学与信息技术研究院合肥 230601;
d 中国科学技术大学合肥微尺度物质科学国家研究中心合肥 230026;
e 清华大学生命科学学院清华大学-北京大学生命科学联合中心北京 100084;
f 清华大学生命科学学院生物信息学教育部重点实验室北京 100084

投稿日期:2020-04-30 发布日期:2020-05-07
通讯作者: 甘自保, 伍志鲲 E-mail:zbgan@iim.ac.cn;zkwu@issp.ac.cn
基金资助:
项目受国家自然科学基金（Nos.21925303，21971246，21829501，21905284，21771186，21603234，21222301，21171170，21528303）、中国博士后科学基金会（Y94G4E356B）、中国科学院合肥研究院院长基金（BJPY2019A02）、中科院合肥物质科学研究院“十三五”规划重点支持项目（KP-2017-16）、中国科学院/国家外国专家局创新团队国际合作伙伴计划和合肥物质科学技术中心方向项目培育基金（2017FXCX002）资助.

Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process

Jin Fengming^a,b,c, Dong Hongwei^a,b,c, Zhao Yan^a,b,c, Zhuang Shengli^a,c, Liao Lingwen^a,c, Yan Nan^a,c, Gu Wanmiao^a,b,c, Zha Jun^a,b,c, Yuan Jinyun^d, Li Jin^e, Deng Haiteng^f, Gan Zibao^a,c, Yang Jinlong^d, Wu Zhikun^a,c

a Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;
b University of Science and Technology of China, Hefei 230026, China;
c Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;
d Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China;
e Tsinghua University-Peking University Joint Center for Life Sciences, School of Life Sciences, Tsinghua University, Beijing 100084, China;
f MOE Key Laboratory of Bioinformatics, School of Life Sciences, Tsinghua University, Beijing 100084, China

Received:2020-04-30 Published:2020-05-07
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21925303, 21971246, 21829501, 21905284, 21771186, 21603234, 21222301, 21171170, 21528303), China Postdoctoral Science Foundation (Y94G4E356B), CASHIPS Director's Fund (BJPY2019A02), Key Program of 13th five-year plan, CASHIPS (KP-2017-16), CAS/SAFEA International Partnership Program for Creative Research Teams and Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology (2017FXCX002).

1. Supporting_Information-A20040134.pdf(1032KB)

Abstract

Precisely modulating the structure of nanoparticles in a controlled manner is still a challenging and inspiring topic. Although the single or few-metal atom tailoring of gold nanoparticles has been reported, local structural replacement involving over three net metal atoms (module replacement, MR) has not been hitherto achieved. Herein, we report the synthesis of cyclohexanethiolated metal nanoclusters (NCs) Au₄₈(CHT)₂₆ and their MR by a so-called pseudo-anti-galvanic reaction (AGR) process. The MR product Au₃₇(CHT)₂₃ shares a similar Au₃₁(CHT)₁₂ unit with its predecessor Au₄₈(CHT)₂₆; however, it differs from its predecessor in the remaining section (Au₆(CHT)₁₁ vs. Au₁₆(CHT)₁₄), as revealed by single-crystal X-ray crystallography (SCXC). Interestingly, the MR inhibits the photothermy but enhances the emission of Au₄₈(CHT)₂₆ NCs, which might endow the as-obtained NC better potential for bi(multiple)-functional application. The counter effects of the MR on the emission and photothermy indicate that photoluminescence and photothermy can be at least partly converted into each other, which has some important implications for the understanding of their interaction.

Key words: gold nanoparticles, module replacement, pseudo-anti-galvanic reaction (AGR), photothermy, photoluminescence

Cite this article

Jin Fengming, Dong Hongwei, Zhao Yan, Zhuang Shengli, Liao Lingwen, Yan Nan, Gu Wanmiao, Zha Jun, Yuan Jinyun, Li Jin, Deng Haiteng, Gan Zibao, Yang Jinlong, Wu Zhikun. Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process[J]. Acta Chimica Sinica, 2020, 78(5): 407-411.

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通过赝反伽伐尼反应实现金纳米粒子模块替换

Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process

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