Polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) Copolymers: Synthesis and Fabrication of Their Porous Films

doi:10.6023/A1112264

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (9): 1125-1130.DOI: 10.6023/A1112264 Previous Articles Next Articles

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聚苯乙烯-co-聚(2,3,4,5,6-五氟苯乙烯)共聚物: 合成及其多孔薄膜的制备

吕会朝^a, 张成潘^a,b, 黄晋^a, 赵巧玲^a, 马志^a, 肖吉昌^a,b

a. 中国科学院上海有机化学研究所上海 200032;
b. 中国科学院有机氟化学重点实验室中国科学院上海有机化学研究所上海 200032

投稿日期:2011-12-26 修回日期:2012-03-07 发布日期:2012-05-18
通讯作者: 马志; 肖吉昌 E-mail:mazhi728@sioc.ac.cn; jchxiao@sioc.ac.cn
基金资助:
中国科学院有机氟化学重点实验室开放基金资助项目.

Polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) Copolymers: Synthesis and Fabrication of Their Porous Films

Lü Huichao^a, Zhang Chengpan^a,b, Huang Jin^a, Zhao Qiaoling^a, Ma Zhi^a, Xiao Jichang^a,b

a. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;
b. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2011-12-26 Revised:2012-03-07 Published:2012-05-18
Supported by:
Project supported by Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

Well-defined polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) (PS-co-PPFS) copolymers were synthesized by atomic transfer radical polymerization (ATRP) in trifluorotoluene, fluorinated ionic liquid and trifluorotoluene/fluorinated ionic liquid solvent systems, respectively. The chain structure and component of such copolymers were characterized by ¹H NMR, ¹⁹F NMR, elemental analysis and GPC. Porous films of PS-co-PPFS copolymers were fabricated by static breath-figure method in CS₂, CHCl₃ and CH₂Cl₂, respectively. The morphologies of such porous films were observed by scanning electron microscopy (SEM) and compared with those of PS homopolymer with similar molecular weight. The results showed that PS-co-PPFS copolymers with narrow molecular weight distribution (M_n＝5200～7900 g·mol^-1, i>M_w/M_n＝ 1.12～1.22) can be synthesized via ATRP in trifluorotoluene and fluorinated ionic liquid, respectively. The SEM observation indicated that PS-co-PPFS copolymer porous films can be fabricated with CS₂, CHCl₃ and CH₂Cl₂ as solvent, respectively. While, different from PS analogues, PS-co-PPFS copolymer porous films showed less ordered pore structures with two different average pore sizes. The pores of such film fabricated in CHCl₃ were in better order with two average pore sizes of 0.75 and 0.37 μm, respectively.

Key words: polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) copolymer, atomic transfer radical polymerization, breath figure, porous film

Cite this article

Lü Huichao, Zhang Chengpan, Huang Jin, Zhao Qiaoling, Ma Zhi, Xiao Jichang. Polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) Copolymers: Synthesis and Fabrication of Their Porous Films[J]. Acta Chimica Sinica, 2012, 70(9): 1125-1130.

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1 Krafft, M. P. J. Polym. Sci., Part A: Polym. Chem. 2006, 44,4251.

2 Krafft, M. P.; Riess, J. G. Chem. Rev. 2009, 109, 1714.

3 Nurmi, L.; Kontturi, K.; Houbenov, N.; Laine, J.; Ruokolainen, J.; Seppala, J. Langmuir 2010, 26, 15325.

4 Lou, L. P.; Koike, Y.; Okamoto, Y. J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 4938.

5 Yuan, Y.; Zhang, M. Z.; Zhang, H.; Ni, P. H. Acta Chim. Sinica 2010, 68, 1537 (in Chinese). (袁媛, 张明祖, 张虎, 倪沛红, 化学学报, 2010, 68,1537.)

6 Li, X. Y.; Qiu, N.; Li, X. X.; Han, Z. W. Acta Chim. Sinica2011, 69, 1425 (in Chinese). (李晓艳, 仇年, 李欣欣, 韩哲文, 化学学报, 2011, 69,1425.)

7 Hulteen, J. C.; Jirage, K. B.; Martin, C. R. J. Am. Chem. Soc. 1998, 120, 6603.

8 Lu, X. Y.; Zhang, C. C.; Han, Y. C. Macromol. Rapid Commun. 2004, 25, 1606.

9 Yabu, H.; Shimomura, M. Langmuir 2005, 21, 1709.

10 Yabu, H.; Takebayashi, M.; Tanaka, M.; Shimomura, M. Langmuir 2005, 21, 3235.

11 Yabu, H.; Shimomura, M. Chem. Mater. 2005, 17, 5231.

12 Beattie, D.; Wong, K. H.; Williams, C.; Poole-Warren, L. A.; Davis, T. P.; Barner-Kowollik, C.; Stenzel, M. H. Biomacromolecules2006, 7, 1072.

13 Jin, J.; Wan, L. S.; Ke, B. B.; Xu, Z. K. Prog. Chem. 2010,22, 2173 (in Chinese). (金晶, 万灵书, 柯蓓蓓, 徐志康, 化学进展, 2010, 22,2173.)

14 Li, L.; Zhong, Y. W.; Chen, C. K.; Li, J. Acta Phys.-Chim. Sin. 2010, 26, 1135 (in Chinese). (李磊, 钟雅文, 陈财康, 李剑, 物理化学学报, 2010, 26,1135.)

15 Du, M. C.; Zhu, P. L.; Yan, X. H.; Su, Y.; Song, W. X.; Li, J. B. Chem. Eur. J. 2011, 17, 4238.

16 Wan, L.-S.; Li, J. W.; Ke, B. B.; Xu, Z. K. J. Am. Chem. Soc. 2012, 134, 95.

17 Widawski, G.; Rawiso, M.; Fran?ois, B. Nature 1994, 369,387.

18 Bunz, U. H. F. Adv. Mater. 2006, 18, 973.

19 Stenzel, M. H.; Barner-Kowollik, C.; Davis, T. P. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 2363.

20 Connal, A.; Qiao, G. G. Adv. Mater. 2006, 18, 3024.

21 Bolognesi, A.; Mercogliano, C.; Yunus, S. Langmuir 2005,21, 3480.

22 Cheng, C. X.; Tian, Y.; Shi, Y. Q.; Tang, R. P.; Xi, F. Langmuir 2005, 21, 6576.

23 Wong, K. H.; Davis, T. P.; Barner-Kowollik, C. J.; Stenzel, M. H. Polymer 2007, 48, 4950.

24 Dong, W. Y.; Zhou, Y. F.; Yan, D. Y.; Mai, Y. Y.; He, L.; Jin, C. Y. Langmuir 2009, 25, 173.

25 Li, L.; Chen, C. K.; Zhang, A. J.; Liu, X. Y.; Cui, K.; Huang, J.; Ma, Z.; Han, Z. H. J. Colloid Interface. Sci.2009, 331, 446.

26 Li, L.; Zhong, Y. W.; Ma, C. Y.; Li, J.; Chen, C. K.; Zhang, A. J.; Tang, D. L.; Xie, S. Y.; Ma, Z. Chem. Mater. 2009,21, 4977.

27 Ma, C. Y.; Zhong, Y. W.; Li, J.; Chen, C. K.; Gong, J. L.; Xie, S. Y.; Li, L.; Ma, Z. Chem. Mater. 2010, 22, 2367.

28 Li, L.; Li, J.; Zhong, Y. W.; Chen, C. K.; Ben, Y.; Gong, J. L.; Ma, Z. J. Mater. Chem. 2010, 20, 5446.

29 Li, L.; Zhong, Y. W.; Gong, J. L.; Li, J.; Chen, C. K.; Zeng, B. R.; Ma, Z. Soft Matter 2011, 7, 546.

30 Li, J.; Zhao, Q. L.; Chen, J. Z.; Li, L.; Huang, J.; Ma, Z.; Zhong, Y. W. Polym. Chem. 2010, 1, 164.

31 Li, Q. Z.; Zhang, G. Y.; Chen, J. Z.; Zhao, Q. L.; Lu, H. C.; Huang, J.; Wei, L. H.; D’Agaosto, F.; Boisson, C.; Ma, Z. J. Polym. Sci. Part A: Polym. Chem. 2011, 49, 511.

32 Li, Q. Z.; Zhang, G. Y.; Huang, J.; Zhao, Q. L.; Wei, L. H.; He, Z. H.; Ma, Z. Acta Chim. Sinica 2011, 69, 497 (in Chinese). (李启蒸, 张国艺, 黄晋, 赵巧玲, 魏柳荷, 何占航, 马志, 化学学报, 2011, 69, 497.)

33 Lu, H. C.; Xu, S. G.; Zhao, Q. L.; Huang, J.; Cao, S. K.; Ma, Z. Acta Chim. Sinica 2011, 69, 1126 (in Chinese). (吕会朝, 徐慎刚, 赵巧玲, 黄晋, 曹少魁, 马志, 化学学报, 2011, 69, 1126.)

34 Geng, F. H.; Chen, J. Z.; Zhao, Q. L.; Li, J.; Ma, Z. Acta Chim. Sinica 2011, 69, 2741 (in Chinese). (耿风华, 陈健壮, 赵巧玲, 李剑, 马志, 化学学报, 2011,69, 2741.)

35 Zhang, C. P.; Wang, Z. L.; Chen, Q. Y.; Zhang, C. T.; Gu, Y. F.; Xiao, J. C. Eur. J. Inorg. Chem. 2010, 22, 3419.

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聚苯乙烯-co-聚(2,3,4,5,6-五氟苯乙烯)共聚物: 合成及其多孔薄膜的制备

Polystyrene-co-poly(2,3,4,5,6-pentafluoro styrene) Copolymers: Synthesis and Fabrication of Their Porous Films

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