Synthesis and Properties of Sn30Co30C40 Ternary Alloy Anode Material for Lithium Ion Battery

doi:10.6023/A13030268

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (07): 1011-1016.DOI: 10.6023/A13030268 Previous Articles Next Articles

Communications

锂离子电池Sn₃₀Co₃₀C₄₀三元合金负极材料的制备与性能研究

刘欣^a, 解晶莹^b, 赵海雷^a,c, 王可^b, 汤卫平^b, 潘延林^b, 丰震河^b, 吕鹏鹏^a

a 北京科技大学材料科学与工程学院北京 100083;
b 上海空间电源研究所上海 200245;
c 新能源材料与技术北京市重点实验室北京 100083

投稿日期:2013-03-12 发布日期:2013-05-02
通讯作者: 解晶莹, E-mail: xiejingying2007@126.com;赵海雷, hlzhao@ustb.edu.cn. E-mail:xiejingying2007@126.com; hlzhao@ustb.edu.cn.
基金资助:
项目受国家基础研究(973, No. 2013CB934003);国家自然科学基金(21273019);上海市科技人才计划(No. 12XD1421900)和上海市科委科技创新项目(Nos. 10dz2250900, 12dz1200503)资助.

Synthesis and Properties of Sn₃₀Co₃₀C₄₀ Ternary Alloy Anode Material for Lithium Ion Battery

Liu Xin^a, Xie Jingying^b, Zhao Hailei^a,c, Wang Ke^b, Tang Weiping^b, Pan Yanlin^b, Feng Zhenhe^b, Lv Pengpeng^a

a School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083;
b Shanghai Institute of Space Power Sources, Shanghai 200245;
c Beijing Key Lab of New Energy Materials and Technology, Beijing 100083

Received:2013-03-12 Published:2013-05-02
Supported by:
Project supported by the National Key Basic Research Development Program of China (973 special preliminary study plan, No. 2013CB934003), the National Natural Science Foundation of China (No. 21273019), Shanghai Science and Technology Talent Project Funds (No. 12XD1421900) and Shanghai Science and Technology Development Funds (Nos. 10dz2250900, 12dz1200503).

1. Synthesis and Properties of Sn₃₀Co₃₀C₄₀ Ternary Alloy Anode Material for Lithium Ion Battery.PDF(188KB)

Abstract

With the development of advanced lithium ion batteries, electrode materials with higher capacity are urgently in demand. With respect to the anode materials, Sn-based alloy materials with high theoretical capacity (990 mAh/g) have the potential to replace the traditional, low capacity carbon-based materials. However, the practical application of Sn-based anode materials is severely retarded due to the poor cycling stability of electrode, which is believed to be caused by the pulverization of active particles resulting from the large volume of Sn during lithiation/delithiation process. The Sn-Co-C ternary alloy with amorphous or nano microstructure can overcome this problem and therefore display attractive electrochemical performance, including high capacity and good cycle stability. In the present work, amorphous Sn₃₀Co₃₀C₄₀ alloy material was synthesized through a simple and scalable two-step method (carbothermal reduction-high energy ball milling method). CoSn₂ alloy was firstly prepared by the carbothermal reduction route from low cost metal oxide and activated carbon. Then the prepared CoSn₂ were mixed with metal cobalt and graphite in a molar ratio of 3:3:8 via a high energy ball milling process to synthesize the final Sn₃₀Co₃₀C₄₀ material. The preferential synthesis of CoSn₂ alloy was important to get Sn₃₀Co₃₀C₄₀material with much smaller CoSn grain dispersed in carbon matrix and thus critical to the better electrochemical performance. XRD, SEM, TEM, HR-TEM, S-TEM and electrochemical tests were used to evaluate the structure and electrochemical performance of the CoSn₂ and Sn₃₀Co₃₀C₄₀materials. The synthesized Sn₃₀Co₃₀C₄₀ material displayed micro-sized particle morphology, which in fact was composed of 10 nm CoSn grains distributed well in amorphous carbon matrix. The Sn₃₀Co₃₀C₄₀ material showed high specific capacity of 550 mAh/g with an initial coulombic efficiency of 80%, good cycling stability and excellent rate-capability. The specific capacity of 430, 380, 280 mAh/g could be achieved at the rate of 1 C, 2 C and 5 C, respectively.

Key words: Sn₃₀Co₃₀C₄₀, carbothermal reduction-high energy ball milling, electrochemical performance, alloy anode, lithium ion battery

Cite this article

Liu Xin, Xie Jingying, Zhao Hailei, Wang Ke, Tang Weiping, Pan Yanlin, Feng Zhenhe, Lv Pengpeng. Synthesis and Properties of Sn₃₀Co₃₀C₄₀ Ternary Alloy Anode Material for Lithium Ion Battery[J]. Acta Chimica Sinica, 2013, 71(07): 1011-1016.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Etacheri, V.; Marom, R.; Elazari, R.; Salitra, G.; Aurbach, D. Energy Environ. Sci. 2011, 4, 3243.
[2] Zhang, W. J. J. Power Sources 2011, 196, 13.
[3] Gao, P.; Yang, J. Porg. Chem. 2011, 23, 264. (高鹏飞, 杨军, 化学进展, 2011, 23, 264.)
[4] Guo, B.; Chi, M.; Sun, X. G.; Dai, S. J. Power Sources 2012, 205, 495.
[5] Ko, S.; Lee, J. I.; Yang, H. S.; Park, S.; Jeong, U. Adv. Mater. 2012, 24, 4451.
[6] http://www. sony. net/SonyInfo/News/Press/200502/05-006E/.
[7] http://www. sony. com. cn/news_center/press_release/techonology/1955_3787. htm.
[8] Dahn, J. R.; Mar, R. E.; Abouzeid, A. J. Electrochem. Soc. 2006, 153(2), A361.
[9] Todd, A. D. W.; Mar, R. E.; Dahn, J. R. J. Electrochem. Soc. 2007, 154(6), A597.
[10] Ferguson, P. P.; Todd, A. D. W.; Dahn, J. R. Electrochem. Commun. 2008, 10, 25.
[11] Ferguson, P. P.; Rajora, M.; Dunlap, R. A.; Dahn, J. R. J. Electrochem. Soc. 2009, 156(3), A204.
[12] Ferguson, P. P.; Martine, M. L.; Dunlap, R. A.; Dahn, J. R. Electrochim. Acta 2009, 54, 4534.
[13] Todd, A. D. W.; Dunlap, R. A.; Dahn, J. R. J. Alloys Compd. 2007, 443, 114.
[14] Ferguson, P. P.; Todd, A. D. W.; Dahn, J. R. Electrochem. Commun. 2010, 12, 1041.
[15] Tian, Y.; Timmons, A.; Dahn, J. R. J. Electrochem. Soc. 2009, 156, A187.
[16] Li, M. Y.; Liu, C. L.; Shi, M. R.; Dong, W. S. Electrochim. Acta 2011, 56, 3023.
[17] Cui, W.; Wang, F.; Wang, J.; Wang, C.; Xia, Y. Electrochim. Acta 2011, 56, 4812.
[18] Chen, Z.; Qian, J.; Ai, X.; Cao, Y.; Yang, H. J. Power Sources 2009, 189, 730.
[19] Zhai, C.; Du, N.; Zhang, H.; Yu, J.; Wu, P.; Xiao, C.; Yang, D. Nanoscale 2011, 3, 1798.
[20] Nacimiento, F.; Alcántara, R.; Nwokeke, U. G.; González, J. R.; Tirado, J. L. Ultrason. Sonochem. 2012, 19, 352.
[21] Yang, S.; Shen, D.; Wu, X. Adv. Mater. Res. 2011, 299～300, 516.
[22] He, J.; Zhao, H.; Wang, M.; Jia, X. Mater. Sci. Eng. B 2010, 171, 35.
[23] Lavela, P.; Nacimiento, F.; Ortiz, G. F.; Tirado, J. L. J. Solid State Electrochem. 2010, 14, 139.
[24] Yan, R. B.; Ren, J. G.; Zhao, H. L.; He, X. M.; Pu, W. H. Chin. J. Power Sources 2010, 24, 803. (闫润宝, 任建国, 赵海雷, 何向明, 蒲薇华, 电源技术, 2010, 24, 803.)
[25] Hassoun, J.; Panero, S.; Mulas, G.; Scrosati, B. J. Power Sources 2007, 171, 928.
[26] Hassoun, J.; Mulas, G.; Panero, S.; Scrosati, B. Electrochem. Commun. 2007, 9, 2075.
[27] Hassoun, J.; Ochal, P.; Panero, S.; Mulas, G.; Minella, C. B.; Scrosati, B. J. Power Sources 2008, 180, 568.
[28] Lee, S.; Yoon, S.; Park, C. M.; Lee, J. M.; Kim, H.; Im, D.; Doo, S. G.; Sohn, H. J. Electrochim. Acta 2008, 54, 364.
[29] Guo, H.; Zhao, H.; Jia, X.; Li, X.; Qiu, W. Electrochim. Acta 2007, 52, 4853.
[30] Guo, H.; Zhao, H.; Jia, X. Electrochem. Commun. 2007, 9, 2207.
[31] Guo, H.; Zhao, H.; Yin, C.; Qiu, W. J. Alloys Compd. 2007, 426, 277.
[32] Shi, Y.; Guo, B.; Corr, S. A.; Shi, Q.; Hu, Y. S.; Heier, K. R.; Chen, L.; Seshadri, R.; Stucky, G. D. Nano Lett. 2009, 9, 4215.
[33] Nyten, A.; Abouimrane, A.; Armand, M.; Gustafsson, T.; Thomas, J. O. Electrochem. Commun. 2005, 7, 156.
[34] Zhang, W. J. J. Power Sources 2011, 196, 877.
[35] Todd, A. D. W.; Ferguson, P. P.; Fleischauer, M. D.; Dahn, J. R. Int. J. Energy Res. 2010, 34, 535.

锂离子电池Sn₃₀Co₃₀C₄₀三元合金负极材料的制备与性能研究

Synthesis and Properties of Sn₃₀Co₃₀C₄₀ Ternary Alloy Anode Material for Lithium Ion Battery

PDF

Supporting Info.

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ping Li, Qiyu Yang, Jing Zeng, Ran Zhang, Qiuyan Chen, Fei Yan. Effect of Fluorine Doping on the Performance of Reversible Solid Oxide Cells and Related Kinetic Studies [J]. Acta Chimica Sinica, 2024, 82(1): 36-45.
[2]	Shikun Liu, Chengwei Deng, Feng Ji, Yulin Min, Hexing Li. Design and Study on Pore Structure of Cathode Double Catalytic Layer in High-temperature Proton Exchange Membrane Fuel Cell^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1135-1141.
[3]	Wenchao Bi, Linfeng Zhang, Jian Chen, Ruixue Tian, Hao Huang, Man Yao. Lithiation Mechanism and Performance of Monoclinic ZnP₂ Anode Materials [J]. Acta Chimica Sinica, 2022, 80(6): 756-764.
[4]	Yanli Li, Dandan Yu, Sen Lin, Dongfei Sun, Ziqiang Lei. Preparation of α-MnO₂ Nanorods/Porous Carbon Cathode for Aqueous Zinc-ion Batteries [J]. Acta Chimica Sinica, 2021, 79(2): 200-207.
[5]	Qimei Liang, Yujiao Guo, Junming Guo, Mingwu Xiang, Xiaofang Liu, Wei Bai, Ping Ning. Preparation and High Temperature Electrochemical Performance of LiNi_0.08Mn_1.92O₄ Cathode Material of Submicron Truncated Octahedron [J]. Acta Chimica Sinica, 2021, 79(12): 1526-1533.
[6]	Liu Jiuding, Zhang Yudong, Liu Junxiang, Li Jinhan, Qiu Xiaoguang, Cheng Fangyi. In-situ Li₃PO₄ Coating of Li-Rich Mn-Based Cathode Materials for Lithium-ion Batteries [J]. Acta Chimica Sinica, 2020, 78(12): 1426-1433.
[7]	Ren Xuqiang, Li Donglin, Zhao Zhenzhen, Chen Guangqi, Zhao Kun, Kong Xiangze, Li Tongxin. Dual Effect of Aluminum Doping and Lithium Tungstate Coating on the Surface Improves the Cycling Stability of Lithium-rich Manganese-based Cathode Materials [J]. Acta Chimica Sinica, 2020, 78(11): 1268-1274.
[8]	Song Xuexi, Li Jicheng, Li Zhaohui, Li Xifei, Ding Yanhuai, Xiao Qizhen, Lei Gangtie. Effect of K-Doping on the Sodium-storage Performance of Sodium Vanadate Nanoplates [J]. Acta Chim. Sinica, 2019, 77(7): 625-633.
[9]	Chang Shilei, Liang Feng, Yao Yaochun, Ma Wenhui, Yang Bin, Dai Yongnian. Research Progress of Metallic Carbon Dioxide Batteries [J]. Acta Chim. Sinica, 2018, 76(7): 515-525.
[10]	Liu Qingchao, Ma Shiyu, Xu Jijing, Li Zhongjun, Zhang Xinbo. Design and Preparation of Advanced Materials for Lithium-Air Batteries [J]. Acta Chimica Sinica, 2017, 75(2): 137-146.
[11]	Yang Chun, Gong Zhengliang, Zhao Wengao, Yang Yong. Synthesis and Electrochemical Performance of Lithium Rich Cathode Materials xLi₃NbO₄·(1-x)LiMO₂ (M=Mn, Co; 0 < x < 1) for Li-ion Batteries [J]. Acta Chim. Sinica, 2017, 75(2): 212-217.
[12]	Xia Lan, Yu Linpo, Hu Di, Chen Z. George. Research Progress and Perspectives on High Voltage, Flame Retardant Electrolytes for Lithium-Ion Batteries [J]. Acta Chim. Sinica, 2017, 75(12): 1183-1195.
[13]	Kong Lijuan, Zhou Xiaoyan, Fan Saiying, Li Zaijun, Gu Zhiguo. Study on the Synthesis and Electrochemical Performance of Histidine-Functionalized Graphene Quantum Dots@Silicon Composite Anode Material [J]. Acta Chim. Sinica, 2016, 74(7): 620-628.
[14]	Ren Tong, Zhuang Quanchao, Hao Yuwan, Cui Yongli. Influence of Electrochemical Performance of Lithium Ion Batteries with the Adding of LiF and LiCl [J]. Acta Chim. Sinica, 2016, 74(10): 833-838.
[15]	Wan Gang, Fu Yu'ang, Guo Jianing, Xiang Zhonghua. Photoelectronic Porous Covalent Organic Materials: Research Progress and Perspective [J]. Acta Chim. Sinica, 2015, 73(6): 557-578.

锂离子电池Sn30Co30C40三元合金负极材料的制备与性能研究