Preparation, Characterization of Ru/AlOOH Catalyst and Its Benzene Partial Hydrogenation Behavior

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (18): 1765-1770. Previous Articles Next Articles

Ru/AlOOH催化剂的制备、表征及其苯选择加氢反应的研究

王建强, 郭平均, 乔明华, 闫世润, 范康年

复旦大学化学系, 上海市分子催化与功能材料重点实验室, 上海, 200433

投稿日期:2004-03-22 修回日期:2004-08-13 发布日期:2014-02-17
通讯作者: 范康年,E-mail:mhqiao@fudan.edu.cn;knfan@fudan.edu.cn E-mail:mhqiao@fudan.edu.cn;knfan@fudan.edu.cn
基金资助:
国家重点基础研究发展"973"规划(No.G2000048009),国家自然科学基金(No.20203004)和上海市科委(No.03QB14004)资助项目

Preparation, Characterization of Ru/AlOOH Catalyst and Its Benzene Partial Hydrogenation Behavior

WANG Jian-Qiang, GUO Ping-Jun, QIAO Ming-Hua, YAN Shi-Run, FAN Kang-Nian

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433

Received:2004-03-22 Revised:2004-08-13 Published:2014-02-17

Abstract

A novel 4 wt% Ru/AlOOH catalyst was prepared by the coprecipitation method and characterized by XRD, TG/DTA, TEM and nitrogen physisorption. In liquid phase benzene partial hydrogenation, Ru/AlOOH catalyst exhibited much higher cyclohexene selectivity and moderate activity than Ru/γ-Al₂O₃ catalyst prepared by calcining the titled catalyst or by the wetness impregnation method. It is suggested that the surface hydroxyl groups and the large pores in boehmite be essential for a high yield of cyclohexene.

Key words: benzene, cyclohexene, hydrogenation, Ru,Ru/AlOOH, ore structure

Cite this article

WANG Jian-Qiang, GUO Ping-Jun, QIAO Ming-Hua, YAN Shi-Run, FAN Kang-Nian. Preparation, Characterization of Ru/AlOOH Catalyst and Its Benzene Partial Hydrogenation Behavior[J]. Acta Chimica Sinica, 2004, 62(18): 1765-1770.

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Ru/AlOOH催化剂的制备、表征及其苯选择加氢反应的研究

Preparation, Characterization of Ru/AlOOH Catalyst and Its Benzene Partial Hydrogenation Behavior

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