Crystal Structure, Fluorescence Characterization of Dysprosium(Ⅲ) Multicomponent Complex with Acylhydrazone and 1, 1O-Phenanthroline

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (20): 2040-2044. Previous Articles Next Articles

镝(Ⅲ)与酰腙及1,10菲啰啉多元配合物的晶体结构及荧光性质

杨锐^1,2, 何水样¹, 武望婷¹, 文振翼¹, 史启祯¹, 王大奇³

1. 西北大学化学系, 陕西省物理无机化学重点实验室, 西安, 710069;
2. 宁夏大学化学化工学院, 银川, 750021;
3. 聊城大学化学系, 聊城, 252059

投稿日期:2004-03-03 修回日期:2004-04-30 发布日期:2014-02-17
通讯作者: 何水样,E-mail:xdhsy@263.net E-mail:xdhsy@263.net
基金资助:
陕西省自然科学基金(No.2002B05)及陕西省教育厅专项基金(No.03JK085)资助项目.

Crystal Structure, Fluorescence Characterization of Dysprosium(Ⅲ) Multicomponent Complex with Acylhydrazone and 1, 1O-Phenanthroline

YANG Rui^1,2, HE Shui-Yang¹, WU Wang-Ting¹, WEN Zhen-Yi¹, SHI Qi-Zhen¹, WANG Da-Qi³

1. Department of Chemistry, Northwest University and Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Xi'an 710069;
2. College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021;
3. Department of Chemistry, Liaocheng University, Liaocheng 252059

Received:2004-03-03 Revised:2004-04-30 Published:2014-02-17

Abstract

Dysprosium(Ⅲ) complex with 2-oxo-propionic acid salicyloyl hydrazone (C₁₀H₁₀N₂O₄) and 1,10-phenanthroline (C₁₂H₈N₂, phen) has been synthesized. The yellow prismatic crystal complex crystallizes in the monoclinic system with space group P2₁/c and parameters a=1.524(3) nm, b=1.1018(19) nm, c=1.468(3) nm, β=92.28(2)°, V=24.63(7) nm³, Z=4, μ=3.100 mm^-1, D_c=1.831 g/cm³, F(000)=1340, R=0.0314, (wR=)0.0660, GOF=0.966. Dysprosium atom is 9-coordinated by carboxyl and carbonyl O atoms and N atom of one tridentate C₁₀H₁₀N₂O₄ ligand to form two stable five-membered rings with the same edge, and the other coordinated atoms coming from one bidentate phen, one bidentate nitrate and two water molecules. The coordination polyhedron around Dy³⁺ was described as a monocapped square antiprism. There is a lattice water molecule in the crystal cell. Luminescence measurement shows that the complex emits fluorescence.

Key words: dysprosium(Ⅲ)complex, 2-oxo-propionic acid salicyloyl hydrazone, 1,10-phenanthroline, crystal structure, fluorescence characterization

Cite this article

YANG Rui, HE Shui-Yang, WU Wang-Ting, WEN Zhen-Yi, SHI Qi-Zhen, WANG Da-Qi. Crystal Structure, Fluorescence Characterization of Dysprosium(Ⅲ) Multicomponent Complex with Acylhydrazone and 1, 1O-Phenanthroline[J]. Acta Chimica Sinica, 2004, 62(20): 2040-2044.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Paschalidis, D. G.; Tossidis, I. A.; Gdaniec, M. Polyhedron2000, 19, 2629.
[2] Yang, Z.-Y.; Yang, R.-D.; Li, F.-S.; Yu, K.-B.Polyhedron 2000, 19, 2599.
[3] Deng, R.-W.; Wu, J.-G.; Chen, Z.-N. Synth. React. Met.-Org. Chem. 1992, 22, 1295.
[4] He, S.-Y.; Yang, R.; Cao, W.-K.; Gu, A.-P.; Shi, Q.-Z.; Wang, Z.-M.; Yan, C.-H. Acta Chim. Sinica 2003, 61,715 (in Chinese).(何水样,杨锐,曹文凯,顾爱萍,史启祯,王哲明,严纯华,化学学报,2003,61,715.)
[5] Cao, W.-K.; He, S.-Y.; Zhao, J.-S.; Yang, R.; Shi, Q.-Z.; Wang, D.-Q.; Dou, J.-M. Acta Chim. Sinica 2003, 61,1612 (in Chinese).(曹文凯,何水样,赵建社,杨锐,史启祯,王大奇,窦建民,化学学报,2003,61,1612.)
[6] He, S.-Y.; Cao, W.-K.; Chen, J.-L.; Zhao, J.-S.; Shi,Q.-Z. Chem. J. Chin. Univ. 2002, 23, 991 (in Chinese).(何水样,曹文凯,陈军利,赵建设,史启祯,高等学校化学学报,2002,23,991.)
[7] He, S.-Y.; Cao, W.-K.; Yang, R.; Zhao, J.-S.; Shi, Q.-Z.; Wang, Z.-M.; Yan, C.-H. Chin. J. Inorg. Chem.2003, 19, 699 (in Chinese).(何水样,曹文凯,杨锐,赵建社,史启祯,王哲明,严纯华,无机化学学报,2003,19,699.)
[8] He, S.-Y.; Liu, Y.; Zhao, J.-S.; Zhao, H.-A.; Yang, R.;Hu, R.-Z.; Shi, Q.-Z. Chin. J. Chem. 2003, 21, 139.
[9] Jiang, Z.-C.; Cai, R.-X.; Zhang, H.-S. Analytical Chemistry of Rare Earth Element, 2nd ed., Science Press, Beijing, 2000,p. 224 (in Chinese).(江祖成,蔡汝秀,张华山,稀土元素分析化学(第二版),科学出版社,北京,2000,p.224.)
[10] Bertolasi, V.; Gilli, P.; Ferretti, V.; Gilli, G.; Vaughan, K.;Jollimore, J. V. Acta Crystallogr., Sect. B: Struct. Sci. 1999,B55, 994.
[11] Xu, X.-J.; Tang, Y.-Q. Chin. J. Inorg. Chem. 2000, 16,157 (in Chinese).(徐筱杰,唐有祺,无机化学学报,2000,16,157.)
[12] Li, G.-Z. Fluorescerce Analytical Method, Science Press,Beiiing, 1991 (in Chinese).(李国珍,荧光分光分析法,科学出版社,北京,1991.)

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[3]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[4]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[5]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[6]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[7]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[8]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[9]	Dong Lu, Zheng Chunying, Zhou Pei, Shi Rufei, Li Hui. Advances in Crystallography of Coordination Complexes on Main Group Metals with Amino Acid Ligands [J]. Acta Chimica Sinica, 2014, 72(9): 981-1000.
[10]	Han Cong, Xu Zhe, Diao Chunhua, Chen Xin, Liu Jing, Guo Minjie, Fan Zhi. Self-assembly Behavior of Interlocked Helical Supramolecule of Cyclodextrin Modified by 2-Furanmethanethiol [J]. Acta Chimica Sinica, 2013, 71(03): 439-442.
[11]	Duan Xianying, Guo Libing, Wang Jianli. A Good Proton-conductive Polyoxometalate Complex {[Co(H₂O)₈][H(H₂O)₃](HINO)₄(PW₁₂O₄₀)}_n: Synthesis, Crystal Structure and Properties [J]. Acta Chimica Sinica, 2013, 71(01): 107-113.
[12]	Guo Qiong, Li Lianzhi, Dong Jianfang, Liu Hongyan, Xue Zechun, Xu Tao . Synthesis, Crystal Structure and Interactions with DNA and BSA of a Oxovanadium(IV) Complex [VO(o-Van-Asn)(Phen)]?1.5CH₃OH [J]. Acta Chimica Sinica, 2012, 70(15): 1617-1624.
[13]	Lu Yanmei, Ou Zhibin, Hu Wei, Le Xueyi. Structure, Antibacterial Activities and DNA Cleavage of a Copper(II) Complex with 2-(2'-Pyridyl)benzimidazole and L-Alaninate [J]. Acta Chimica Sinica, 2012, 70(08): 973-979.
[14]	Lu Dongfei, Di Youying, Dou Jianmin. Synthesis, Crystal Structure and Low-temperature Heat Capacities of Bis(n-undecylammonium)tetrachlorocadmiumate [J]. Acta Chimica Sinica, 2012, 70(07): 889-896 .
[15]	Tang Zhan, Yang Li, Qiao Xiaojing, Zhang Tonglai, Zhang Jianguo, Liang Yanhui. Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO₃ and (AIM)(HTNR)稨₂O [J]. Acta Chimica Sinica, 2012, 0(04): 471-478.

镝(Ⅲ)与酰腙及1,10菲啰啉多元配合物的晶体结构及荧光性质

Crystal Structure, Fluorescence Characterization of Dysprosium(Ⅲ) Multicomponent Complex with Acylhydrazone and 1, 1O-Phenanthroline

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments