Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate※

doi:10.6023/A22010012

Acta Chimica Sinica ›› 2022, Vol. 80 ›› Issue (6): 703-707.DOI: 10.6023/A22010012 Previous Articles Next Articles

Special Issue: 中国科学院青年创新促进会合辑

Communication

富晶格位错的多孔铋纳米花高效电还原二氧化碳制甲酸盐^※

蒋银龙^a^,^b, 李国超^a^,^b, 陈青松^b^,^*(), 徐忠宁^b, 林姗姗^a^,^b, 郭国聪^b^,^*()

a 福州大学化学学院福州 350116
b 中国科学院福建物质结构研究所结构化学国家重点实验室福州 350002

投稿日期:2022-01-06 发布日期:2022-07-07
通讯作者: 陈青松, 郭国聪
作者简介:
^※ 庆祝中国科学院青年创新促进会十年华诞.
基金资助:
国家重点研发计划项目(2017YFA0206802); 国家重点研发计划项目(2017YFA0700103); 国家自然科学基金(21203200); 国家自然科学基金(91545201)

Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate^※

Yinlong Jiang^a^,^b, Guochao Li^a^,^b, Qingsong Chen^b(), Zhongning Xu^b, Shanshan Lin^a^,^b, Guocong Guo^b()

a College of Chemistry, Fuzhou University, Fuzhou 350116, China
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2022-01-06 Published:2022-07-07
Contact: Qingsong Chen, Guocong Guo
About author:
^※ Dedicated to the 10th anniversary of the Youth Innovation Promotion Association, CAS.
Supported by:
National Key R&D Program of China(2017YFA0206802); National Key R&D Program of China(2017YFA0700103); National Natural Science Foundation of China(21203200); National Natural Science Foundation of China(91545201)

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Abstract

The conversion of carbon dioxide has become a hot topic in the world today. Here, we adopt the strategy of in-situ electrochemical transformation to reduce layered bismuth oxide formate nanoflowers (BiOCOOH NFs) self-assembled with nanosheets synthesized by simple solvothermal method to porous bismuth nanoflowers (p-Bi NFs) with a large number of lattice dislocations. Specifically, 1.0 g Bi(NO₃)₃•5H₂O was ultrasonically dissolved in 10 mL N,N-dimethylformamide (DMF), then 70 mL deionized water was added to the above solution, and the resulting solution was ultrasonicated for 10 min at room temperature to ensure that all reagents were uniformly dispersed. The resulting solution was then transferred to a 100 mL Teflon-lined stainless steel autoclave, kept at 120 ℃ for 20 h, and then naturally cooled to room temperature. The results show that the minimum overpotential of the electrochemical reduction of carbon dioxide to formate is 436 mV. When the catalyst loading is 0.5 mg/cm², the partial current density of formate (j_formate) is as high as 24.4 mA•cm^-2, which is 5.5 times that of commercial bismuth (Commercial Bi); and the Faraday efficiency (FE_formate) of formate is 96.7% at –1.8 V versus saturated calomel electrode (vs. SCE). The FE_formate is over 90% in a wide potential window of over 500 mV. Moreover, the p-Bi NFs electrocatalyst is stable in formate production for more than 10 h in CO₂-saturated 0.5 mol•L^-1 KHCO₃ electrolyte. Compared with the normalized electrochemical surface area (ECSA), it was found that the j_formate of p-Bi NFs was still about 4.5 times higher than that of Commercial Bi. The high catalytic performance of the catalyst can be attributed to the unique micro/nano hybrid structure derived from the lattice collapse and reconstruction of precursors, resulting in porous and rough surface and containing high density of active sites with lattice dislocations and defects. This study provides new insights into designing and synthesizing electrocatalysts with high performance for carbon dioxide reduction to formate.

Key words: bismuth, electrocatalysis, carbon dioxide, formate, lattice dislocation

Cite this article

Yinlong Jiang, Guochao Li, Qingsong Chen, Zhongning Xu, Shanshan Lin, Guocong Guo. Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate^※[J]. Acta Chimica Sinica, 2022, 80(6): 703-707.

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Fig. & Tab. 3

Figure 1. Schematic of the synthesis process of p-Bi NFs

Figure 2. Structure characterization of BiOCOOH NFs and p-Bi NFs. XRD images of BiOCOOH NFs and p-Bi NFs (a); SEM (b), TEM (c) and HRTEM (d) images of p-Bi NFs. (e) and (f) are respectively the magnification of the white square region (1) and (2) as indicated in (d)

Figure 3. Measurement of electrochemical carbon dioxide reduction performance in H type cell. Linear scanning voltammetric curves (LSV) of p-Bi NFs and Commercial Bi in CO2 and Ar saturated 0.5 mol•L-1 KHCO3 solution (a); comparison of formate current density (b) and Faraday efficiency (c) of p-Bi NFs and Commercial Bi with potential variation; stability test of p-Bi NFs (d); comparison of electrochemical impedance spectroscopy (EIS) (e) and Tafel curve (f) of p-Bi NFs and Commercial Bi

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富晶格位错的多孔铋纳米花高效电还原二氧化碳制甲酸盐^※

Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate^※

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富晶格位错的多孔铋纳米花高效电还原二氧化碳制甲酸盐※

Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate※

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PDF

Supporting Info.

Knowledge

Abstract

Cite this article

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Fig. & Tab. 3

References 31

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富晶格位错的多孔铋纳米花高效电还原二氧化碳制甲酸盐^※

Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate^※