手性膦小分子催化不对称反应的研究进展

doi:10.6023/cjoc201210017

摘要/Abstract

手性膦小分子催化的不对称反应是目前研究的热点之一, 该类反应具有反应时间短、条件温和、催化活性高、环境友好等优点, 符合绿色化学发展方向. 对手性膦小分子催化的不对称Morita-Baylis-Hillman反应、Morita-Baylis-Hillman加成物的烯丙基位立体选择性取代反应、环加成反应、酯化反应, γ-加成反应以及其它重要的不对称反应进行简要的评述.

关键词: 手性膦小分子催化, Morita-Baylis-Hillman反应, 不对称反应

Enantioselective phosphine organocatalysis has been a research frontier in the field of asymmetric catalysis. The comparable advantages, including short reaction time, mild reaction conditions, high catalytic activity, and environment benign, render the organocatalytic reaction to meet the development direction of green chemistry. This paper briefly reviews the recent advances in the development of chiral phosphine-catalyzed asymmetric reactions, such as Morita-Baylis-Hillman reaction, the asymmetric allylic substitution of Morita-Baylis-Hillman adducts, cycloaddition, esterification reaction, γ-addition reaction and other asymmetric reaction.

Key words: enantioselective phosphine organocatalysis, Morita-Baylis-Hillman reaction, asymmetric reaction

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唐谦, 涂爱平, 邓真真, 胡梦莹, 钟为慧. 手性膦小分子催化不对称反应的研究进展[J]. 有机化学, 2013, 33(05): 954-970.

Tang Qian, Tu Aiping, Deng Zhenzhen, Hu Mengying, Zhong Weihui. Progress in Enantioselective Phosphine Organocatalysis[J]. Chin. J. Org. Chem., 2013, 33(05): 954-970.

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