D-A-π-A结构染料敏化剂研究进展

doi:10.6023/cjoc201504006

有机化学 ›› 2015, Vol. 35 ›› Issue (11): 2237-2258.DOI: 10.6023/cjoc201504006 上一篇下一篇

综述与进展

D-A-π-A结构染料敏化剂研究进展

杨贺玮^a,b, 官俊杰^a,b, 高峰贤^a,b, 何欣平^a,b, 王安^a,b, 孙宝德^a,b, 张学强^a,b, 张宝^a, 冯亚青^a,b

a 天津大学化工学院天津 300072;
b 天津大学天津化工协同创新中心天津 300072

收稿日期:2015-04-07 修回日期:2015-06-27 发布日期:2015-07-08
通讯作者: 张宝 E-mail:baozhang@tju.edu.cn
基金资助:
国家自然科学基金(Nos. 21476162, 21076147)及科技部国际合作(No. 2012DFG41980)资助项目.

Research Progress on the Application of D-A-π-A Featured Sensitizer in the Dye Sensitized Solar Cells

Yang Hewei^a,b, Guan Junjie^a,b, Gao Fengxian^a,b, He Xinping^a,b, Wang An^a,b, Sun Baode^a,b, Zhang Xueqiang^a,b, Zhang Bao^a, Feng Yaqing^a,b

a School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072;
b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300072

Received:2015-04-07 Revised:2015-06-27 Published:2015-07-08
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21476162, 21076147) and the National International S&T Cooperation Foundation of China (No. 2012DFG41980).

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摘要/Abstract

D-π-A结构基于对分子内光生电子传输的增强作用而成为了敏化太阳能电池(dye sensitized solar cells, DSSCs)敏化剂设计的主要出发点. D-A-π-A结构的敏化剂是从D-π-A结构出发, 在敏化剂的内部引入附加的吸电子基团作为内部电子受体而设计出来的, 相比于传统的D-π-A结构敏化剂在性能上具有更大的优势. 综述了2012年以来科学家对D-A-π-A结构敏化剂的分子设计及其在DSSCs中的应用性能的研究成果.

关键词: D-A-π-A, 太阳能电池, 敏化剂

The donor-π bridge-acceptor (D-π-A) configuration becomes mainstream in the design of organic sensitizers due to its enhancement of the intramolecular photo-generated charge-transfer. On the basis of traditional D-π-A structure, researchers incorporate additional electron-withdrawing unites into the π bridge as internal acceptor, termed as D-A-π-A configuration, which displays better performance. This review summarizes the molecular design (since 2012) of sensitizers based on D-A-π-A configuration and their application in the dye sensitized solar cells.

Key words: D-A-π-A, solar cell, sensitizer

引用此文

杨贺玮, 官俊杰, 高峰贤, 何欣平, 王安, 孙宝德, 张学强, 张宝, 冯亚青. D-A-π-A结构染料敏化剂研究进展[J]. 有机化学, 2015, 35(11): 2237-2258.

Yang Hewei, Guan Junjie, Gao Fengxian, He Xinping, Wang An, Sun Baode, Zhang Xueqiang, Zhang Bao, Feng Yaqing. Research Progress on the Application of D-A-π-A Featured Sensitizer in the Dye Sensitized Solar Cells[J]. Chin. J. Org. Chem., 2015, 35(11): 2237-2258.

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D-A-π-A结构染料敏化剂研究进展

Research Progress on the Application of D-A-π-A Featured Sensitizer in the Dye Sensitized Solar Cells

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