含全氟环丁基芳基醚结构的疏水性聚碳酸酯的合成及性能研究

doi:10.6023/cjoc201812048

有机化学 ›› 2019, Vol. 39 ›› Issue (9): 2639-2644.DOI: 10.6023/cjoc201812048 上一篇下一篇

研究论文

含全氟环丁基芳基醚结构的疏水性聚碳酸酯的合成及性能研究

胡丹^a, 赵昆峰^a,b,c, 童琴^a,b, 何丹农^a,b,c

a 纳米技术及应用国家工程研究中心上海 200241;
b 上海交通大学材料科学与工程学院上海 200240;
c 上海健康医学院上海 201318

收稿日期:2018-12-28 修回日期:2019-03-26 发布日期:2019-04-11
通讯作者: 童琴, 何丹农 E-mail:hdn_nercn@163.com;tongqin_7557@163.com
基金资助:
国家重大科学研究计划（No.2015CB931902）和上海市青年科技启明星计划（B类）（No.16QB1402200）资助项目.

Synthesis and Properties of Perfluorocyclobutyl Aryl Ether-Based Hydrophobic Polycarbonate

Hu Dan^a, Zhao Kunfeng^a,b,c, Tong Qin^a,b, He Dannong^a,b,c

a National Engineering Research Center for Nanotechnology, Shanghai 200241;
b School of Material Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240;
c Shanghai University of Medicine & Health Sciences, Shanghai 201318

Received:2018-12-28 Revised:2019-03-26 Published:2019-04-11
Contact: 10.6023/cjoc201812048 E-mail:hdn_nercn@163.com;tongqin_7557@163.com
Supported by:
Project supported by the Major National Scientific Research Projects (No. 2015CB931902) and the Shanghai Science and Technology Development Funds (No. 16QB1402200).

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摘要/Abstract

以商业化的对羟基苯甲醚为原料，合成了一种新型的含有全氟环丁基芳基醚结构的疏水性聚碳酸酯.该聚合物在不降低材料透明性的前提下，表现出了优异的热稳定性和疏水性，其热分解温度为351℃，涂膜与水的接触角为110°.为了进一步探究全氟环丁基芳基醚结构对聚碳酸酯的性能影响，以含有全氟环丁基芳基醚结构的单体和双酚A单体为原料，合成了一系列具有不同全氟环丁基芳基醚基团含量的聚碳酸酯.通过性能比较可知，将全氟环丁基芳基醚结构引入聚碳酸酯，能够降低聚碳酸酯的分散度，提高其热稳定性和疏水性.

关键词: 聚碳酸酯, 疏水性, 全氟环丁基芳基醚

A novel hydrophobic polycarbonate containing perfluorocyclobutyl (PFCB) aryl ether was synthesized from commercially available p-methoxyphenol. The polymer exhibited excellent thermal stability and hydrophobicity without reducing the transparency of the material. The thermal decomposition temperature was 351℃ and the contact angle between the film and water was 110°. In order to further explore the effect of PFCB aryl ether structure on the properties of polycarbonate, a series of polycarbonates with different PFCB aryl ether group contents were synthesized from PFCB aryl ether monomer and bisphenol A monomer. By comparing their properties, the introduction of PFCB aryl ether structure into polycarbonate can reduce its dispersion and improve its thermal stability and hydrophobicity.

Key words: polycarbonate, hydrophobicity, perfluorocyclobutyl aryl ether

引用此文

胡丹, 赵昆峰, 童琴, 何丹农. 含全氟环丁基芳基醚结构的疏水性聚碳酸酯的合成及性能研究[J]. 有机化学, 2019, 39(9): 2639-2644.

Hu Dan, Zhao Kunfeng, Tong Qin, He Dannong. Synthesis and Properties of Perfluorocyclobutyl Aryl Ether-Based Hydrophobic Polycarbonate[J]. Chin. J. Org. Chem., 2019, 39(9): 2639-2644.

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含全氟环丁基芳基醚结构的疏水性聚碳酸酯的合成及性能研究

Synthesis and Properties of Perfluorocyclobutyl Aryl Ether-Based Hydrophobic Polycarbonate

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