塔[5]芳烃: 一种具有深穴与规整空腔的新型蒽基大环芳烃

doi:10.6023/cjoc202100035

有机化学 ›› 2021, Vol. 41 ›› Issue (5): 2141-2142.DOI: 10.6023/cjoc202100035 上一篇下一篇

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塔[5]芳烃: 一种具有深穴与规整空腔的新型蒽基大环芳烃

王彦方¹, 蒋伟¹^,^*()

1 南方科技大学化学系广东深圳 518055

发布日期:2021-05-27
通讯作者: 蒋伟

Pagoda[5]arene: An Emerging Anthracene-Based Macrocyclic Arene with a Deep and Well-Defined Cavity

Yanfang Wang¹, Wei Jiang¹^,^*()

1 Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055

Published:2021-05-27
Contact: Wei Jiang
About author:
* Corresponding author. E-mail: jiangw@sustech.edu.cn.

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王彦方, 蒋伟. 塔[5]芳烃: 一种具有深穴与规整空腔的新型蒽基大环芳烃[J]. 有机化学, 2021, 41(5): 2141-2142.

Yanfang Wang, Wei Jiang. Pagoda[5]arene: An Emerging Anthracene-Based Macrocyclic Arene with a Deep and Well-Defined Cavity[J]. Chinese Journal of Organic Chemistry, 2021, 41(5): 2141-2142.

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图式1. (a)塔[4]芳烃、异塔[4]芳烃和塔[5]芳烃的合成路线和(b) (邻二氯苯)2@塔[5]芳烃的单晶结构(蓝色虚线表示C—H…π相互作用)

Scheme 1. (a) Synthetic procedures of pagoda[4]arene, i-pagoda[4]arene and pagoda[5]arene, and (b) crystal structures of (o-DCB)2@pagoda[5]arene (blue dotted lines indicate C—H…π interactions)

图1. 柱[5]芳烃、棱[5]芳烃和塔[5]芳烃的(a)化学结构与(b)单晶结构

Figure 1. (a) Chemical structures and (b) crystal structures of pillar[5]arene, prism[5]arene and pagoda[5]arene

图2. 塔[5]芳烃与(a)双质子化的4,4'-联吡啶或(b)质子化的2-甲氧基苯基吡啶形成的三元复合物的单晶结构

Figure 2. Crystal structures of the ternary complexes of pagoda[5]arene with (a) two doubly protonated 4,4'-bispyridines or (b) two protonated 2-methoxylphenyl pyridines

参考文献 10

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塔[5]芳烃: 一种具有深穴与规整空腔的新型蒽基大环芳烃

Pagoda[5]arene: An Emerging Anthracene-Based Macrocyclic Arene with a Deep and Well-Defined Cavity

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