有机化学 ›› 1992, Vol. 12 ›› Issue (4): 411-418. 上一篇    下一篇

研究论文

取代环戊二烯基锂芳酰化的研究

焦纶基;马玉适;李吉海;刘金亭   

  1. 山东大学应用化学系
  • 发布日期:1992-08-25

Aroylation of substituted cyclopentadienyllithium

JIAO LUNJI;MA YUSHI;LI JIHAI;LIU JINTING   

  • Published:1992-08-25

本文研究了由616-二烷基富烯与有机锂所制得取代环戊二烯基锂和芳酰氯的反应,合成了二十个未见文献报道的新富烯类化合物,并通过^1HNMR、IR和元素分析确定了它们的结构.

关键词: 红外分光光度法, 芳酰氯, 元素分析, 环戊二烯 P, 有机锂化合物, 质子磁共振谱法, 富烯

Direct aroylation of substituted cyclopentadienyllithiums, prepared from Me or Ph lithium and 6,6-dialkylfulvene, with aroyl chloride was described and twenty new substituted fulvenes were synthesized. E.g., fulvene I was prepared in 48.3% yield from 6,6-dimethylfulvene, PhLi, and BzCl.

Key words: ELEMENTAL ANALYSIS, INFRARED SPECTROPHOTOMETRY, FULVENE, CYCLOPENTADIENE P, ORGANO LITHIUM COMPOUNDS, PROTON MAGNETIC RESONANCE SPECTROMETRY

中图分类号: