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有机化学
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有机化学 ›› 1994, Vol. 14 ›› Issue (2): 153-158. 上一篇    下一篇

研究论文

1-烷基-4,6-二芳基四氢三嗪硫酮化合物的合成及其氧化反应

任平达;贾韵仪;董庭威   

  1. 复旦大学化学系
  • 发布日期:1994-04-25

Synthesis and oxidation of 1-alkyl-4,6-diaryl- tetrahydro-S-triazine-2(1H)-thiones

Ren Pingda;JIA YUNYI;DONG TINGWEI   

  • Published:1994-04-25

被引次数

5

三芳基缩二胺与烷基硫脲在二氧六环回流条件下反应, 可生成1-烷基-4,6-二芳基四氢三嗪硫酮化合物3。利用芳香醛, 烷基硫脲和醋酸铵一锅法也能得到3, 而三芳基缩二胺与芳基硫脲反应, 则生成了咪唑啉的硫氰酸盐。室温下,在相转移催化剂TEBA存在时, 3可被高锰酸钾氧化, 得到1-烷基-4,6-二芳基-2(1H)三嗪酮化合物。

关键词: 氧化反应, 三嗪酮, 硫酮化合物, 单取代硫脲, 三芳基缩二胺, 四氢三嗪硫酮

1-alkyl-4,6-diaryl-tetrahydro-S-triazine- 2(1H)-thiones 3 were prepared by reactions of N,N'-diarylmethylenearylmethanediamines with alkylthioureas, or by mixing arylaldehyde. alkylthioureas and ammonium acetate in one pot process. Amarinethiocynate was obtained by reactions of N,N'-diarylmethylenearylme- thanediamines with arylthioureas. 3 have been oxidized to 1-alkyl-4,6-diaryl-S-triazine-2(1H)- ones by potassium permanganate in the presence of TEBA at room temperature.

Key words: TRIAZONE, OXIDATION REACTION

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