有机化学 ›› 2000, Vol. 20 ›› Issue (1): 122-130. 上一篇    

研究论文

有机同系物性质的递变规律研究

聂长明;范明舫   

  1. 中南工学院化学工程系
  • 发布日期:2000-02-25

Regularity of physicochemical properties for homologous organic compounds

Nie Changming;Fan Mingfang   

  • Published:2000-02-25

以有机同系物结构重复单元数值连续变化为模型,得到同系物行质递变的两个基本规律:P=a+bn和P=c+kln(n+a/n+b),a,b,c,k均为常数,n为结构重复单元数值,P为同系物的物性。一般地,加和型性能遵守直线变化规律,而结构型和凝聚型性能遵守同系对数线性规律。

关键词: 同系物, 递变规律, 物理化学性能, 同系线性规律

With the model that the number of repeating units of the homologous series varies successively, two fundamental relationships have been developed: P=a+bn and P=c+kln n=a/n+b Where a、b、c、k all refer to the constants, n to the number of repeating units, P tothe properties for homogolous series. Generally, additive type properties conform to thelinear relationship, adn the structural - type properties and condened - type properties tothe homololgous logarithmic linear relationship.

Key words: HOMOLOG, CHANGE LOW, PHYSICAL CHEMISTRY PROPERTY, HOMOLOGOUS LINEARITY RULE

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