含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展

有机化学 ›› 2004, Vol. 24 ›› Issue (1): 29-33. 上一篇下一篇

综述与进展

含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展

廉兵, 黄吉玲^*, 钱延龙, 陈琦辉

华东理工大学金属有机化学研究室上海 200237

收稿日期:2003-01-10 修回日期:2003-03-19 接受日期:2003-06-03 发布日期:2022-09-21
基金资助:
国家重大基础研究(No. G1999064801)、国家自然科学基金(No. 20072004)、高等学校博士点专项科研基金和华东理工大学博士学位论文创新行动计划(2003年)资助项目.

Progress in Synthesis of Group 4 Complex with Cp and Non-Cp Mixed Ligands and Their Catalytic Application for α-Olefin Polymerization

LIAN Bing, HUANG Ji-Ling^*, QIAN Yan-Long, CHEN Qi-Hui

Laboratory of Organometallic Chemistry, East China University of Science and Technology, Shanghai 200237

Received:2003-01-10 Revised:2003-03-19 Accepted:2003-06-03 Published:2022-09-21
Contact: *E-mail: qianling@online.sh.cn

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摘要/Abstract

目前金属有机钛族络合物的发展呈现出多元化的趋势:茂络合物、非茂络合物以及茂非茂混合配体络合物,而其中茂、非茂混合配体络合物是近年来发展的一个新亮点.关于茂钛族络合物、非茂钛族络合物近年已经有过许多的综述,而关于茂、非茂混合配体钛族络合物的综述却很少.综述了近年来茂、非茂混合配体钛族络合物合成与催化烯烃聚合的研究进展.

关键词: 茂、非茂混合配体, 钛族络合物, 烯烃聚合

The progresses ofgroup 4 complex exhibit multi-trends: Cp complex, non-Cp complex and complex with Cp and non-Cp mixed ligands. Among them, the complex with Cp and non-Cp mixed ligands is a new shining-point. In recent years, there are many reviews about Cp complex or non-Cp complex, but there is few review regarding the complexwith Cp and non-Cp mixed ligands. This paper reviews the latest progress in thesynthesis of group 4 complexes with Cp and non-Cp mixed ligands and their catalytic application for olefin polymerization.

Key words: Cp and non-Cp mixed ligand, group 4 complex, olefin polymerization

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廉兵, 黄吉玲, 钱延龙, 陈琦辉. 含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展[J]. 有机化学, 2004, 24(1): 29-33.

LIAN Bing, HUANG Ji-Ling, QIAN Yan-Long, CHEN Qi-Hui. Progress in Synthesis of Group 4 Complex with Cp and Non-Cp Mixed Ligands and Their Catalytic Application for α-Olefin Polymerization[J]. Chinese Journal of Organic Chemistry, 2004, 24(1): 29-33.

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含茂、非茂混合配体钛族络合物的合成与催化烯烃聚合的研究进展

Progress in Synthesis of Group 4 Complex with Cp and Non-Cp Mixed Ligands and Their Catalytic Application for α-Olefin Polymerization

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