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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (12): 1580-1582. 上一篇    下一篇

研究简报

E-3-二茂铁基-2-丙烯醛的简便合成方法

连小春，杜计燕，温孟赢，孙真荣，汤杰*   

  1. (1华东师范大学化学系 上海 200062)
    (2华东师范大学光谱学与波谱学教育部重点实验室 上海 200062)
  • 收稿日期:2005-01-20 修回日期:2005-06-02 发布日期:2005-11-30
  • 通讯作者: 汤杰

Practical Preparation of E-3-Ferrocenyl-2-propenal Using Diethyl 2-(Cyclohexylamino)vinylphosphonate

LIAN Xiao-Chun, DU Ji-Yan, WEN Meng-Ying, SUN Zhen-Rong, TANG Jie*   

  1. (1 Department of Chemistry, East China Normal University, Shanghai 200062)
    (2 Key Laboratory of Optical and Magnetic Resonance Spectroscopy, Ministry of Education,
    East China Normal University, Shanghai 200062)
  • Received:2005-01-20 Revised:2005-06-02 Published:2005-11-30
  • Contact: TANG Jie

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由二茂铁甲醛和Nagata试剂通过Wittig-Horner反应生成反式二茂铁丙烯醛. 该方法以易得的原料、温和的反应条件和高收率制备了目标产物.

关键词: 二茂铁甲醛, E-3-二茂铁基-2-丙烯醛, Nagata试剂, Wittig-Horner反应

A practical procedure for preparation of E-3-ferrocenyl-2-propenal was developed from ferrocene carboxaldehyde and Nagata’s reagent to provide the target product in high yield under mild conditions.

Key words: E-3-ferrocenyl-2-propenal, ferrocene carboxaldehyde, Wittig-Horner reaction, Nagata’s reagent