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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (9): 1100-1102. 上一篇    下一篇

研究简报

上新世华山松化石中的甾体化合物

赵友兴1，李承森2，罗晓东1，扆铁梅2，周俊*,1   

  1. (1中国科学院昆明植物研究所植物化学与西部植物资源国家重点实验室 昆明 650204)
    (2中国科学院植物研究所 北京 100093)
  • 收稿日期:2004-10-30 修回日期:2005-03-14 发布日期:2005-08-24
  • 通讯作者: 周俊

Steroids from Pliocene Fossil Pinus armandii

ZHAO You-Xing1,LI Cheng-Sen2,LUO Xiao-Dong1,YI Tie-Mei2,ZHOU Jun*,1   

  1. (1 State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany,
    Chinese Academy of Sciences, Kunming 650204)
    (2 Institute of Bot-any, Chinese Academy of Sciences, Beijing 100093)
  • Received:2004-10-30 Revised:2005-03-14 Published:2005-08-24
  • Contact: ZHOU Jun

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被引次数

28

从上新世华山松(Pliocene Pinus armandii)化石木中分离鉴定了5个甾体成分: 24ξ-n-丙基-胆甾烷-3-酮(1), 豆甾 烷-3-酮(2), 24α-乙基-3α-胆甾醇(3), 4-豆甾烯-3-酮(4)和3β-谷甾醇(5). 化合物1为一个新的C30甾体. 它们的结构由波谱方法鉴定.

关键词: 华山松, 上新世, C30-甾体, 化石木

A new C30-steroid, named 24ξ-n-propyl-cholestan-3-one, together with four known steroids, stigmastan-3-one, 24α-ethyl-cholestan-3α-ol, stigmastan-4-en-3-one and 3β-sitosterol was isolated from the pliocene lignified wood of Pinus armandii. Their structures were elucidated on the base of spectroscopic evidence.

Key words: Pinus armandii, pliocene, C30-steroid, fossil wood