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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (08): 1093-1096. 上一篇    下一篇

研究论文

对叔丁基杯[8]芳烃/钼磷杂多酸纳米杂化LB膜的制备与表征

柳利*,1，柳士忠*,1，艾伟河1，黄伦丰1，袁婕2，杜祖亮2   

  1. (1湖北大学化学化工学院 有机功能分子合成与应用教育部重点实验室 武汉 430062)
    (2河南大学特种功能重点实验室 开封 475001)
  • 收稿日期:2005-12-08 修回日期:2006-03-06 发布日期:2006-07-26
  • 通讯作者: 柳利*,a，柳士忠*,a

Preparation and Characterization of Nanohybrid LB Films of tert-Butylcalix[8]arene/Molybdophosphoricheteropolyacids

LIU Li*,1,LIU Shi-Zhong*,1,AI Wei-He1,HUANG Lun-Feng1
YUAN Jie2,DU Zu-Liang2   

  1. (1 Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry of Education,
    Faculty of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062)
    (2 Key Laboratory of Special Functional Materials, Henan University, Kaifeng 475001)
  • Received:2005-12-08 Revised:2006-03-06 Published:2006-07-26
  • Contact: LIU Li*,a, LIU Shi-Zhong*,<

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被引次数

3

以含有共轭大π键的对叔丁基杯[8]芳烃(Cal8)和十八(烷)铵(ODA)与Keggin结构和Dawson结构钼磷杂多酸(HPA)做成膜材料, 用LB技术制备了2种新型无机-有机杂化LB膜. 用π-A曲线、UV-Vis吸收光谱、荧光光谱和原子力显微镜(AFM)对标题LB膜的成膜性质、结构及发光性质进行了表征. 结果表明在空气/水界面Cal8/ODA/HPA杂化可形成稳定的单层与多层膜. 标题杂化LB膜的崩溃压为39.0 mN/m, 其粒子具有纳米尺寸, 在激发波长为280 nm时, 可观察到322～387 nm处由Cal8分子π-π*跃迁引起的荧光发射峰及510 nm处 杂多阴离子的配体到金属的荷移跃迁(LMCT)三重发射谱带.

关键词: 多金属氧酸盐, 表征, 对叔丁基杯[8]芳烃, 制备, LB膜

Two new inorganic-organic hybrid LB films of tert-butylcalix[8]arene (Cal8)/octadecylammo- nium (ODA)/molybdophosphoricheteropolyacids (HPMo12, HP2Mo18) were prepared and characterized by π-A isotherms, UV-Vis absorption spectra, atomic force microscope and fluorescence spectra. The experimental results indicate that title compounds can form stable monolayer and polylayer films on the air/water interface. The collapse pressure of the title LB films was 39.0 mN/m. The fluorescence spectra showed that the emission peak during 322～387 nm was due to the π-π* transition in the Cal8 and the emission peak at 510 nm might correspond to the ligand to metal charge transfer (LMCT) triplet emission of .

Key words: preparation, tert-butylcalix[8]arene, characterization, LB film, polyoxometalate