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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (03): 428-430. 上一篇    

研究简报

松干蚧性信息素Matsuone C(7)～C(13)片段的合成

黄贤贵a，李涛b，林静容b，金荣华a，田伟生*,a,b   

  1. (a上海师范大学生命与环境学院 上海 200234)
    (b中科院上海有机化学研究所 上海 200032)
  • 收稿日期:2006-04-26 修回日期:2006-09-01 发布日期:2007-02-13
  • 通讯作者: 田伟生

Synthesis of the C(7)～C(13) Fragment of Matsuone, a Sex Phero-mone of the Matsucoccus Pine Bast Scales

HUANG Xian-Guia,LI Taob,LIN Jing-Rongb,JIN Rong-Huaa,TIAN Wei-Sheng*,a,b   

  1. (a College of Life Sciences and Enviroment, Shanghai Normal University, Shanghai 200234)
    (b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)
  • Received:2006-04-26 Revised:2006-09-01 Published:2007-02-13
  • Contact: TIAN Wei-Sheng

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被引次数

1

以甾体皂甙元降解工业废弃物中获取的(R)-5-溴-4-甲基戊酸甲酯为原料, 通过三步反应合成了松干蚧性信息素Matsuone的C(7)～C(13)片段-(R)-4,6-二甲基庚醛, 三步合成的总收率为41.6%.

关键词: (R)-5-溴-4-甲基戊酸甲酯, (R)-4,6-二甲基庚醛, Matsuone, 昆虫性信息素

The C(7)～C(13) fragment (R)-4,6-dimethylenanthal of Matsuone, a sex pheromone of the matsu-cocuus pine bast sales, was synthesized starting from the (R)-5-bromo-4-methylvalerate, in 41.6% total yield. The later was prepared from the Industrial waste.

Key words: (R)-5-bromo-4-methylvalerate, (R)-4,6-dimethylenanthal, insect sex pheromone, Matsuone