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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (02): 276-281. 上一篇    下一篇

研究简报

3,9-二氮杂四星烷类化合物的合成研究

朱晓鹤，倪成良，宋秀庆，闫红*，钟儒刚   

  1. (北京工业大学生命科学与生物工程学院 北京 100124)
  • 收稿日期:2009-03-18 修回日期:2009-07-02 发布日期:2010-02-20
  • 通讯作者: 闫红 E-mail:hongyan@bjut.edu.cn
  • 基金资助:

    北京市自然科学基金(No. 200710005002)资助项目；国家自然科学基金（No. 20872009）资助项目;国家级.国家自然科学基金

Synthesis of 3,9-Diazatetraasteranes

Zhu Xiaohe Ni Chengliang Song Xiuqing Yan Hong* Zhong Rugang   

  1. (College of Life Science＆ Bioengineering, Beijing University of Technology, Beijing 100124)
  • Received:2009-03-18 Revised:2009-07-02 Published:2010-02-20

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被引次数

9 | 1

对3,9-二氮杂四星烷(3,9-二氮杂六环[6.4.0.02,7.04,11.05,10]十二烷)的合成进行了系统地研究. 以1,4-二氢吡啶为原料, 研究了溶剂、溶液浓度、光源、照射波长及光照时间等因素对[2＋2]环加成反应的影响, 得到了一系列3,9-二氮杂四星烷化合物, 并用IR, 1H NMR, 13C NMR, MS和HRMS对其结构进行了表征.

关键词: 3,9-二氮杂四星烷, 1,4-二氢吡啶, [2＋2]光环加成

3,9-Diazahexacyclo[6.4.0.02,7.04,11.05,10]dodecanes were synthesized by a head-to-tail [2＋2] photocycloaddition of 1,4-dihydropyridines. Various factors such as solvents, the concentrations of 1,4-dihydropyridine, wavelength of UV and reaction time, were studied in details. An efficient method of synthesizing 3,9-diazatetraasteranes was found, and 12 compounds were ob-tained and characterized by IR, 1H NMR, 13C NMR, MS and HRMS tech-niques.

Key words: 3,9-diazatetraasterane, 1,4-dihydropyridine, [2＋2] photocycloaddition