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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (08): 1195-1201. 上一篇    下一篇

综述与进展

费里尔型重排反应及其在活性分子合成应用中的最新进展

陈沛然*,1,2，向鹏1   

  1. (1东华大学化学化工与生物工程学院 上海 201620)
    (2中国科学院上海有机化学研究所 生命有机化学国家重点实验室 上海 200032)
  • 收稿日期:2011-01-23 修回日期:2011-05-19 发布日期:2011-07-04
  • 通讯作者: 陈沛然 E-mail:prchensioc@hotmail.com

Recent Advances in the Ferrier-type Rearrangement Reactions and Their Applications in the Complex Bio-active Molecules

Chen Peiran*,1,2 Xiang Peng1   

  1. (1 College of Chemistry, Chemical Engineering and Biotechnology, Donghua Univer-sity, Shanghai 201620)
    (2 State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032)
  • Received:2011-01-23 Revised:2011-05-19 Published:2011-07-04
  • Contact: Peiran Chen E-mail:prchensioc@hotmail.com

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对近10年来费里尔型重排反应(包括I型费里尔重排、II型费里尔重排和费里尔-皮塔西斯重排反应)的研究进展作了简要综述, 并介绍了近来费里尔型重排反应应用于复杂的活性分子合成中的研究所取得的进展.

关键词: 费里尔型重排反应, I型费里尔重排, II型费里尔重排, 费里尔-皮塔西斯重排反应, 复杂活性分子合成

Recent advances in the Ferrier-type rearrangement reactions (including type I Ferrier reaction, type II Ferrier reaction and Ferrier-Petasis reaction) are reviewed. The recent applications of these reactions in the synthesis of complex bio-active molecules are also briefly described.

Key words: Ferrier-type rearrangement reaction, type I Ferrier reaction, type II Ferrier reaction, Ferrier-Petasis reaction, synthesis of complex bio-active molecule